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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bøjesen, Espen Drath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Elucidating Structural Disorder in Ultra-Thin Bi-Rich Bismuth Oxyhalide Photocatalystscitations
- 2024Elucidating Structural Disorder in Ultra-Thin Bi-Rich Bismuth Oxyhalide Photocatalystscitations
- 2024Non-monotonic dependence of high-temperature stability of stone wool fibres on pre-oxidation time and temperaturecitations
- 2024Non-monotonic dependence of high-temperature stability of stone wool fibres on pre-oxidation time and temperaturecitations
- 2023The more the better:on the formation of single-phase high entropy alloy nanoparticles as catalysts for the oxygen reduction reactioncitations
- 2022Volume imaging by tracking sparse topological features in electron micrograph tilt series
- 2020Probing the validity of the spinel inversion model: a combined SPXRD, PDF, EXAFS and NMR study of $ZnAl_{2}O_{4}$citations
- 2020Probing the validity of the spinel inversion model:a combined SPXRD, PDF, EXAFS and NMR study of ZnAl 2 O 4citations
- 2017In Situ PDF Study of the Nucleation and Growth of Intermetallic PtPb Nanocrystalscitations
- 2016Crystal structure, microstructure and electrochemical properties of hydrothermally synthesised LiMn2O4citations
- 2016Towards atomistic understanding of polymorphism in the solvothermal synthesis of ZrO2 nanoparticlescitations
- 2014Characterization of the interface between an Fe–Cr alloy and the p-type thermoelectric oxide Ca3Co4O9citations
- 2014Characterization of the interface between an Fe–Cr alloy and the p -type thermoelectric oxide Ca 3 Co 4 O 9citations
- 2013In-situ synchrotron PXRD study of spinel LiMn2O4 nanocrystal formation
- 2013IN-SITU SYNCHROTRON PXRD STUDY OF SPINEL TYPE LiMn2O4 NANOCRYSTAL FORMATION
Places of action
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article
Characterization of the interface between an Fe–Cr alloy and the p-type thermoelectric oxide Ca3Co4O9
Abstract
A customized Fe–Cr alloy that has been optimized for high temperature applications in oxidizing atmospheres has been interfaced via spark plasma sintering (SPS) with a p-type thermoelectric oxide material: calcium cobaltate (Ca3Co4O9). The properties of the alloy have been analyzed for its compatibility with the Ca3Co4O9 in terms of its thermal expansion and transport properties. The thermal and electrical contact resistances have been measured as a function of temperature, and the long term electronic integrity of the interface analyzed by measuring the resistance vs. time at an elevated temperature. The kinetics of the interface have been analyzed through imaging with scanning electron microscopy (SEM), elemental analysis using energy dispersive spectroscopy (EDS), and phase identification with X-ray diffraction (XRD). The results reveal the formation of an intermediate phase containing calcium and chromium in the interface that is highly resistive at room temperature, but conducting at the intended thermoelectric device hot-side operating temperature of 800 °C. As the alloy is well matched in terms of its thermal expansion and highly conducting compared to the Ca3Co4O9, it may be further considered as an interconnect material candidate at least with application on the hot-side of an oxide thermoelectric power generation module.