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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dhawale, Dattatray
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Topics
Publications (9/9 displayed)
- 2013Porous CuO nanosheet clusters prepared by a surfactant assisted hydrothermal method for high performance supercapacitorscitations
- 2012Room temperature novel chemical synthesis of Cu2ZnSnS4 (CZTS) absorbing layer for photovoltaic applicationcitations
- 2011Effect of different modes of electrodeposition on supercapacitive properties of MnO2 thin filmscitations
- 2010Room temperature LPG sensor based on n-CdS/p-polyaniline heterojunctioncitations
- 2010Effect of electron irradiation on properties of chemically deposited TiO2 nanorodscitations
- 2010Conversion of interlocked cube-like Mn3O4 into nanoflakes of layered birnessite MnO2 during supercapacitive studiescitations
- 2010Chemical synthesis and characterization of Mn3O4 thin films for supercapacitor applicationcitations
- 2010Fabrication of copper oxide multilayer nanosheets for supercapacitor applicationcitations
- 2009A novel chemical synthesis of interlocked cubes of hausmannite Mn3O4 thin films for supercapacitor applicationcitations
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article
Conversion of interlocked cube-like Mn3O4 into nanoflakes of layered birnessite MnO2 during supercapacitive studies
Abstract
A facile route based on chemical bath deposition (CBD) from urea containing bath has been developed to deposit the interlocked cubes of hausmannite Mn3O4 electrode for electrochemical supercapacitor application. The as-prepared Mn3O4 electrode showed ideal capacitive behavior during potential cycling within the range of -0.1 to +0.9 V in 1 M Na2SO4 electrolyte. The X-ray diffraction (XRD), scanning electron micrograph (SEM) and Raman scattering (RS) and wettability studies during the supercapacitive stability showed that the interlocked cubes of crystalline Mn3O4 are electrochemically oxidized to nanoflakes of layered birnessite MnO2 due to potential cycling. Due to potential cycling the contact angle of Mn3O4 thin film changed from hydrophilic to superhydrophilic nature. The effect of electrolyte concentration and scan rate on the specific capacitance of so formed MnO2 film has been investigated. Impedance analysis shows that birnessite MnO2 nanoflakes are good conducting than Mn3O4 hence can be used over a wide range of applications. It exhibited highest specific capacitance of 223 F g-1 in 1 M Na2SO4 electrolyte at 5 mV s-1 scan rate and 90% stability after 5000 cycles. © 2010 Elsevier B.V. All rights reserved.