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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Neves, Ic
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Performance of self-cleaning cotton textiles coated with TiO2, TiO2-SiO2 and TiO2-SiO2-HY in removing Rhodamine B and Reactive Red 120 dyes from aqueous solutionscitations
- 2020Binuclear furanyl-azine metal complexes encapsulated in NaY zeolite as efficiently heterogeneous catalysts for phenol hydroxylationcitations
- 2019Photocatalytic performance of N-doped TiO(2)nano-SiO2-HY nanocomposites immobilized over cotton fabricscitations
- 2015Preparation and assessment of antimicrobial properties of bimetallic materials based on NaY zeolitecitations
- 2013Nanocomposites of poly(epsilon-caprolactone) doped with titanium speciescitations
- 2011Encapsulation of alpha-cyano-4-hydroxycinnamic acid into a NaY zeolitecitations
- 2011Stability of nanocomposites of poly(epsilon-caprolactone) with tungsten trioxidecitations
- 2010Enhancement of the Dielectric Constant and Thermal Properties of alpha-Poly(vinylidene fluoride)/Zeolite Nanocompositescitations
- 2009Redox properties of (1-(2-pyridylazo)-2-naphthol)copper(II) encapsulated in Y Zeolitecitations
- 2008Immobilization of Fe(III) complexes of pyridazine derivatives prepared from biosorbents supported on zeolitescitations
- 2008Organic-inorganic hybrid matrix doped with alkenyldiazenido complexes of molybdenumcitations
- 2004Synthesis and immobilization of molybdenum complexes in a pillared layered claycitations
Places of action
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article
Organic-inorganic hybrid matrix doped with alkenyldiazenido complexes of molybdenum
Abstract
New molecular systems based on conjugated groups, trans- [FMo(NNCHCHCHCHCHCH2CH3)(Ph2PCH2CH2PPh2)(2)] [BPh4] have been synthesized and characterized. This complex was immobilized in hybrid organic-inorganic matrix obtained by sol-gel. The hybrid matrix of these organically modified silicates, classified as ureasil formed by poly(oxyethylene) chains [POE, (OCH2CH2)(n)] grafted to siloxane domains by means of urea cross-linkages. All of the new materials were characterized by thermal analysis (DSC), surface analysis (XPS) and spectroscopic methods (FTIR and UV/vis), to gather information on the modifications introduced by the molybdenum complex in hybrid organic-inorganic matrix, as well as on the immobilized complex integrity. The immobilization of the metal complex in the hybrid matrix has kept their integrity, although some distortions can be observed caused by steric effects imposed by the structure of hybrid matrix or/and by interactions between the metal complex and some groups of the hybrid matrix.