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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wójcik, Anna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Adaptive Phase or Variant Formation at the Austenite/Twinned Martensite Interface in Modulated Ni–Mn–Ga Martensitecitations
- 2024Effect of twist-channel angular pressing on precipitation in Al–Mg–Zn–Ga alloys
- 2023Ambient Processed rGO/Ti<sub>3</sub>CNT<sub><i>x</i></sub> MXene Thin Film with High Oxidation Stability, Photosensitivity, and Self-Cleaning Potentialcitations
- 2021Microstructure and magnetic properties of selected laser melted Ni-Mn-Ga and Ni-Mn-Ga-Fe powders derived from as melt-spun ribbons precursorscitations
- 2021Suppression and Recovery of Martensitic Transformation and Magnetism in Mechanically and Thermally Treated Magnetic Shape‐Memory Ni−Mn−Ga Melt‐Spun Ribbonscitations
- 2020Effect of pressure on the phase stability and magnetostructural transitions in nickel-rich NiFeGa ribbonscitations
- 2019Microstructural anisotropy, phase composition and magnetic properties of as-cast and annealed Ni-Mn-Ga-Co-Cu melt-spun ribbonscitations
- 2019The evolution of microstructure and magneto-structural properties of heat treated ni-mn-sn-in heusler alloys sintered by vacuum hot pressing
- 2018Structure and inverse magnetocaloric effect in Ni-Co-Mn-Sn(Si) Heusler alloyscitations
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article
Structure and inverse magnetocaloric effect in Ni-Co-Mn-Sn(Si) Heusler alloys
Abstract
In the presented work, a systematic study of crystal structure, microstructure, magneto-structural behavior and inverse magnetocaloric effect in the Ni44Co6Mn39Sn11-xSix (x = 1, 2 at.%) Heusler alloys, obtained by conventional casting and rapid solidification process, have been performed. All alloys, independently of the chemical composition, i.e. different addition of Si and fabrication process (melt-spinning and induction melting) were fully martensitic at ambient temperature. This was the case in spite of the large difference in the mean grain size of ribbons compared to bulk. Interestingly, the microstructure of ribbons consists of larger grains of about 5–20 μm in diameter with martensitic relief and smaller cells of about 1 μm. The crystal structure of both ribbons and bulk was identified as modulated six-layered (12 M) martensite with five additional spots between main reflections in the reciprocal space. The characteristic temperatures of the martensitic transformation were lower for melt-spun ribbons with respect to bulk. This may be connected with the grain refinement, internal stresses and high density of dislocations caused by rapid solidification process. Moreover, the addition of Si enhances the transformation temperatures. The calculated values of magnetic entropy change were higher for bulk alloys than ribbons