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| Naji, M. |
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Repo, Timo
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Mesoporous silica-amine beads from blast furnace slag for CO<sub>2</sub> capture applicationscitations
- 2023Functionalization of nitrogen-doped graphene quantum dotcitations
- 2022Parahydrogen-induced polarization study of imine hydrogenations mediated by a metal-free catalystcitations
- 2017Nuclear spin hyperpolarization with ansa-aminoboranes : a metal-free perspective for parahydrogen-induced polarizationcitations
- 2016Nuclear spin hyperpolarization with ansa-aminoboranescitations
- 2016Towards improved solubility of poorly water-soluble drugscitations
- 2014Tweezers for Parahydrogencitations
- 2011Two- and three-dimensional packing diagrams of M(salophen) complexescitations
- 2006Synthesis of titanium complexes bearing two mono anionic malonic acid ester based ligands and their use as catalyst precursors in ethene polymerizationcitations
- 2006High-molar-mass polypropene with tunable elastic properties by hafnocene/borate catalystscitations
- 2004Tetrakis Sn(IV) alkoxides as novel initiators for living ring-opening polymerization of lactidescitations
- 2002New bis(imino)pyridine-iron(II)- and cobalt(II)-based catalysts: synthesis characterization and activity towards polymerization of ethylenecitations
- 2002Copolymerization of propene with phenylnorbornene using ansa-bridged metallocene catalystscitations
- 2001Copolymerization of carbon monoxide with exo-methylenecycloalkane and dienes: synthesis of functionalized aliphatic polyketonescitations
- 2000Synthesis and crystal structure of [1-(eta(5)-9-fluorenyl)-2-(eta(5)-1-indenyl)ethane]-hafnium dimethyl
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article
Synthesis of titanium complexes bearing two mono anionic malonic acid ester based ligands and their use as catalyst precursors in ethene polymerization
Abstract
In this work titanium dichloro complexes bearing diethylmalonate, diethylphenylmalonate and diphenylmalonate ligands have been synthesized. The complexes were activated by methylaluminoxane (MAO) and exhibited moderate activity [10-50 kg(PE)/(mol(Ti) h bar)] in ethene polymerization. The catalysts produced ultra high molar mass polyethene (PE) (up to 3000 kg/mol) with polydispersity values range between 2 and 4. (C) 2006 Elsevier B.V. All rights reserved.