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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gastaldi, Emmanuelle
University of Montpellier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2023Monitoring the degradation status of biodegradable polymers by assessing thermal properties
- 2023Compostability of certified biodegradable plastics at industrial scale processing conditions
- 2022Effects of Kraft lignin and corn cob agro-residue on the properties of injected-moulded biocompositescitations
- 2022Effects of Kraft lignin and corn cob agro-residue on the properties of injected-moulded biocompositescitations
- 2020Multi-faceted migration in food contact polyethylene-based nanocomposite packagingcitations
- 2020How Vine Shoots as Fillers Impact the Biodegradation of PHBV-Based Compositescitations
- 2019How olive pomace can be valorized as fillers to tune the biodegradation of PHBV based compositescitations
- 2019A comparative study of degradation mechanisms of PBSA and PHBV under laboratoryscale composting conditionscitations
- 2019New Insights For The Fragmentation Of Plastics Into Microplastics In The Ocean
- 2019Experimental and theoretical study of the erosion of semi-crystalline polymers and the subsequent generation of microparticles.citations
- 2018Fast-Biodegrading polymers
- 2018Soy protein isolate nanocomposite film enriched with eugenol, an antimicrobial agent: Interactions and propertiescitations
- 2018Soy protein isolate nanocomposite film enriched with eugenol, an antimicrobial agent: Interactions and propertiescitations
- 2018Nanostructured biopolymers obtained from blends by extrusion
- 2018How Performance and Fate of Biodegradable Mulch Films are Impacted by Field Ageingcitations
- 2017Contribution of nanoclay to the additive partitioning in polymerscitations
- 2016Effect of nanoclay on the transfer properties of immanent additives in food packagescitations
- 2013Water transport mechanisms in wheat gluten based (nano) composite materialscitations
- 2013Nanoparticle size and water diffusivity in nanocomposite agro-polymer based filmscitations
- 2013Nanoparticle size and water diffusivity in nanocomposite agro-polymer based filmscitations
- 2013Protein-Based Nanocomposites for Food Packagingcitations
- 2013Biocomposites from wheat proteins and fibers: Structure/mechanical properties relationshipscitations
- 2013Adhesion properties of wheat-based particlescitations
- 2012Protein/Clay Nano-Biocompositescitations
- 2011Impact of high pressure treatment on the structure of montmorillonitecitations
- 2010Réduction de l'impact de l’utilisation des produits phytosanitaires: Contrôle de la libération dans le sol par un granulé protéique biodégradable nanocomposite
- 2010Synthesis of nanocomposite films from wheat gluten matrix and MMT intercalated with different quaternary ammonium salts by way of hydroalcoholic solvent castingcitations
Places of action
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article
Biocomposites from wheat proteins and fibers: Structure/mechanical properties relationships
Abstract
For the first time, biocomposites from wheat by-products, i.e. wheat gluten and wheat straw fibers, were prepared using a thermomechanical process. Three types of wheat straw fibers displaying contrasted sizes (median diameter d(50) = 1.1 mm, 62 mu m and 8 mu m), morphologies and surface reactivities were prepared by successive grinding processes (cut milling (CM), impact milling (IM) and ball milling (BM), respectively). The main objectives of the present study were (i) to gain further scientific knowledge about the impact of fibers characteristics on the mechanical properties of these composite materials, and (ii) to evaluate in which extent the addition of wheat straw fibers could decrease the final cost of materials without altering their mechanical properties. Mechanical properties were assessed through tensile tests and discussed in relation to the structure of materials, especially to the interfacial adhesion between the fiber and the matrix. Globally, an increasing fiber content up to 11.1 vol% led to an increase in both the Young's modulus and the stress at break, and to a reduction in the strain at break. Experimental Young's moduli were well predicted by the Tsai-Pagano model for the three types of fibers. Data of specific mechanical energy consumed upon processing, contact angle measurements and observations of cryo-fractured surfaces allowed to demonstrate that the adhesion at the interface wheat straw fiber/wheat gluten was improved by (i) an increased hydrophobicity of wheat straw fibers, which was induced by successive grinding, and (ii) a higher specific surface of fibers which was favoured in the case of small fibers. The interfacial adhesion was improved in the order BM > IM > CM whereas the fiber aspect ratio decreased in the order CM > IM > BM. Thus, a competition between these parameters could occur, explaining why no significant difference in reinforcing effect was achieved between the three types of fibers. Finally, the reinforcing effect of wheat straw fibers was also ascribed to a deplasticizing effect, which was particularly pronounced for BM wheat straw fibers. (C) 2012 Elsevier B.V. All rights reserved.