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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Steinberger-Wilckens, Robert
University of Birmingham
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (38/38 displayed)
- 2023The effects of sintering temperature and current contacting layer on the performance of lanthanum nickelate electrodes in Solid Oxide Fuel Cellscitations
- 2023Experimental and Numerical Evaluation of Polymer Electrolyte Fuel Cells with Porous Foam Distributor
- 2022Evaluation of inkjet-printed spinel coatings on standard and surface nitrided ferritic stainless steels for interconnect application in solid oxide fuel cell devicescitations
- 2022Optimization of a ScCeSZ/GDC bi-layer electrolyte fabrication process for intermediate temperature solid oxide fuel cellscitations
- 2021Five‐layer reverse tape casting of IT‐SOFCcitations
- 2020Corrosion behaviour of nitrided ferritic stainless steels for use in solid oxide fuel cell devicescitations
- 2020In-situ experimental benchmarking of solid oxide fuel cell metal interconnect solutionscitations
- 2020Scattered and linked microcracks in solid oxide fuel cell electrolyte
- 2020Electrochemical performance and carbon resistance comparison between Sn, Cu, Ag, and Rh-doped Ni/ScCeSZ anode SOFCs operated by biogas
- 2020Electrochemical performance of novel NGCO-LSCF composite cathode for intermediate temperature solid oxide fuel cellscitations
- 2020Electrochemical performance of novel NGCO-LSCF composite cathode for intermediate temperature solid oxide fuel cellscitations
- 2020Formulation of Spinel based Inkjet Inks for Protective Layer Coatings in SOFC Interconnectscitations
- 2019Non-crystallising glass sealants for SOFCcitations
- 2019Properties of 10Sc1CeSZ-3.5YSZ(33-, 40-, 50-wt.%) Composite Ceramics for SOFC Applicationcitations
- 2019Ex-situ experimental benchmarking of solid oxide fuel cell metal interconnectscitations
- 2019Ex-situ experimental benchmarking of solid oxide fuel cell metal interconnectscitations
- 2018Influence of temperature and pressure on surface modified Pd-Cu alloy foils for hydrogen purification applicationscitations
- 2018Electrochemical and thermal characterization of doped ceria electrolyte with lanthanum and zirconiumcitations
- 2018Evaluation of Inkjet Printed Protective Layer Coatings for SOFC Interconnects
- 2018X-ray diffraction study on the effects of hydrogen on Pd60Cu40 wt% foil membranescitations
- 2017Modelling Microstructural and Chemical Degradation of Ferritic Stainless Steels for SOFC Interconnects
- 2016Cu-Fe substituted Mn-Co spinels by High Energy Ball Milling for interconnect coatings: insight on sintering properties
- 2016Cu-Fe substituted Mn-Co spinels by High Energy Ball Milling for interconnect coatings: insight on sintering properties
- 2016Thin film perovskite coatings and their application for SOFC ferritic steel interconnects
- 2016Thermochemical and Kinetic Modelling of Chromium-Rich Alloys
- 2016Benchmarking Protective Coatings for SOFC ferritic steel interconnects – The SCORED 2:0 Project
- 2016Cerium-Cobalt-Copper oxides based SOFC anodes for the direct utilisation of methane as fuel
- 2015Investigating electrodes for intermediate temperature polymer electrolyte fuel cell (IT-PEFC)
- 2015Hydrogen selective membranescitations
- 2015Effects of thin film Pd deposition on the hydrogen permeability of Pd60Cu40 wt% alloy membranescitations
- 2015Status of light weight cassette design of SOFCcitations
- 2015Properties of spinel protective coatings prepared using wet powder spraying for SOFC interconnectscitations
- 2014Gas diffusion layer materials and their effect on polymer electrolyte fuel cell performance - Ex situ and in situ characterizationcitations
- 2014Cathodic materials for intermediate-temperature solid oxide fuel cells based on praseodymium nickelates-cobaltitescitations
- 2013On nucleation and growth mechanisms of EBPVD zirconia films on porous NiO-ZrO2 substrate
- 2008Reducing degradation effects in SOFC stacks manufactured at Forschungszentrum Jülich - Approaches and results
- 2005Overview of the development of solid oxide fuel cells at Forschungszentrum Juelich
- 2004Solid oxide fuel cell development at Forschungszentrum Juelich
Places of action
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article
Electrochemical performance of novel NGCO-LSCF composite cathode for intermediate temperature solid oxide fuel cells
Abstract
In this study, a co-dopant CGO was synthesized to produce more efficient cathode materials for intermediate temperature solid oxide fuel cell (IT-SOFC) applications. Neodymium (Nd) was doped into CGO in four different weight ratios in the formula Nd<sub>x</sub>Gd<sub>0.15</sub>Ce<sub>0.85-x</sub>O<sub>2-δ</sub> (NGCO); the selected percentages for x were 1%, 3%, 5% and 7%. XRD patterns showed pure phase for all synthesized compositions and good compatibility at high temperature under static air with the most common ceramic cathode material in IT-SOFC (La<sub>0·60</sub>Sr<sub>0·40</sub>Co0<sub>·20</sub>Fe<sub>0·80</sub>O<sub>2-ä</sub>, LSCF). Impedance spectroscopic characterization of symmetrical cells of the composite NGCO-LSCF at different temperatures (650–800 °C in steps of 50 °C) and a frequency range of 0.1–1 MHz in synthetic air revealed interesting results. The lowest polarization resistance (R<sub>p</sub>) was achieved for Nd<sub>0.05</sub>Gd<sub>0.15</sub>Ce<sub>0·80</sub>O<sub>2-δ</sub> (0.06 Ω cm<sup>2 </sup>at 800 °C, 0.17 Ω cm<sup>2</sup> at 750 °C, 0.31 Ω cm<sup>2</sup> at 700 °C, and 0.59 Ω cm<sup>2</sup> at 650 °C). The expected decrease in Rp was not observed for the sample with higher Nd content (7% Nd). Thus, it can be said that there is a distinction between the compositions Nd<sub>0.05</sub>Gd<sub>0.15</sub>Ce<sub>0·80</sub>O<sub>2-δ</sub> and Nd<sub>0.07</sub>Gd<sub>0.15</sub>Ce<sub>0·78</sub>O<sub>2-δ</sub>; the co-doping of Nd in NGCO incremented the oxygen ion diffusion path, thereby optimization in the triple phase boundary (TPB) sites was obtained. Furthermore, SEM and TGA measurements were conducted to clarify the reasons of such improvements. This work showed that an NGCO-LSCF composite can be considered as a potential candidate for cathode material for future IT-SOFC applications.