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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gibson, Desmond
University of the West of Scotland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Giant piezoelectric effect induced by porosity in inclined ZnO thin filmscitations
- 2024Optical and structural properties of silicon nitride thin films deposited by plasma enhanced chemical vapor deposition for high reflectance optical mirrors
- 2024Non-stoichiometric silicon nitride for future gravitational wave detectorscitations
- 2023Broadband infrared absorber based on a sputter deposited hydrogenated carbon multilayer enhancing MEMS-based CMOS thermopile performancecitations
- 2022High throughput low cost closed field magnetron sputter deposition of durable reflectors based on dielectric overcoated metal for application in non-dispersive infrared gas sensors
- 2022High throughput microwave plasma assisted sputter deposition of linear variable filters and deployment into visible and near infrared spectrometers
- 2021Glancing angle deposition of nanostructured ZnO films for ultrasonicscitations
- 2020Effect of physical activation/surface functional groups on wettability and electrochemical performance of carbon/activated carbon aerogels based electrode materials for electrochemical capacitorscitations
- 2020Durable infrared optical coatings based on pulsed DC-sputtering of hydrogenated amorphous carbon (a-C:H)citations
- 2019Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applicationscitations
- 2018FORMATION OF PIEZOELECTRIC DEVICES
- 2017Influence of europium on structure modification of TiO2 thin films prepared by high energy magnetron sputtering processcitations
- 2017Modification of various properties of HfO2 thin films obtained by changing magnetron sputtering conditionscitations
- 2017Investigation of the antimicrobial properties of modified multilayer diamond-like carbon coatings on 316 stainless steel surface and coatings technologycitations
- 2017Characterisation of Cu2O, Cu4O3, and CuO mixed phase thin films produced by microwave-activated reactive sputteringcitations
- 2017Characterisation of Cu2O/CuO thin films produced by plasma-assisted DC sputtering for solar cell applicationcitations
- 2016Investigation of various properties of HfO2-TiO2 thin film composites deposited by multi-magnetron sputtering systemcitations
- 2016Nanostructured ZnO films prepared by hydro-thermal chemical deposition and microwave-activated reactive sputteringcitations
- 2015Investigation of structural, optical and micro-mechanical properties of (NdyTi1-y)O-x thin films deposited by magnetron sputteringcitations
- 2015The Effect of Growth Conditions on the Surface Energy, Optical Properties and Saline Corrosion Resistance of Amorphous Chromium Oxide Thin Films Prepared by Reactive Magnetron Sputtering
- 2011Large-aperture plasma-assisted deposition of inertial confinement fusion laser coatingscitations
- 2010Large-aperture plasma-assisted deposition of ICF laser coatings
- 2010High ion current density plasma source for ion-assisted deposition of optical thin filmscitations
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article
Effect of physical activation/surface functional groups on wettability and electrochemical performance of carbon/activated carbon aerogels based electrode materials for electrochemical capacitors
Abstract
Polymeric carbon/activated carbon aerogels were synthesized through sol-gel polycondensation reaction followed by the carbonization at 800 °C under Argon (Ar) atmosphere and subsequent physical activation under CO2 environment at different temperatures with different degrees of burn-off. Significant increase in BET specific surface area (SSA) from 537 to 1775 m2g−1 and pore volume from 0.24 to 0.94 cm3g−1 was observed after physical activation while the pore size remained constant (around 2 nm). Morphological characterization of the carbon and activated carbons was conducted using X-ray diffraction (XRD) and Raman spectroscopy. Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to investigate the effect of thermal treatment (surface cleaning) on the chemical composition of carbon samples.<br/><br/>Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to analyse the capacitive and resistive behaviour of non-activated/activated/and surface cleaned activated carbons employed as electroactive material in a two electrode symmetrical electrochemical capacitor (EC) cell with 6 M KOH solution used as the electrolyte.<br/><br/>CV measurements showed improved specific capacitance (SC) of 197 Fg−1 for activated carbon as compared to the SC of 136 Fg−1 when non-activated carbon was used as electroactive material at a scan rate of 5 mVs−1. Reduction in SC from 197 Fg−1 to 163 Fg−1 was witnessed after surface cleaning at elevated temperatures due to the reduction of surface oxygen function groups.<br/><br/>The result of EIS measurements showed low internal resistance for all carbon samples indicating that the polymeric carbons possess a highly conductive three dimensional crosslinked structure. Because of their preferred properties such as controlled porosity, exceptionally high specific surface area, high conductivity and desirable capacitive behaviour, these materials have shown potential to be adopted as electrode materials in electrochemical capacitors.