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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Abbas, Qaisar
University of the West of Scotland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2023Engineering of nickel, cobalt oxides and nickel/cobalt binary oxides by electrodeposition and application as binder free electrodes in supercapacitorscitations
- 2022Development of functional materials for the removal of heavy metals from industrial waste waters
- 2022Graphene synthesis techniques and environmental applicationscitations
- 2022Band gap and pseudocapacitance of Gd2O3 doped with Ni0.5Zn0.5Fe2O4citations
- 2022Structural tuneability and electrochemical energy storage applications of resorcinol-formaldehyde-based carbon aerogelscitations
- 2020Effect of physical activation/surface functional groups on wettability and electrochemical performance of carbon/activated carbon aerogels based electrode materials for electrochemical capacitorscitations
- 2020Pseudocapacitive effect of carbons doped with different functional groups as electrode materials for electrochemical capacitorscitations
- 2019Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applicationscitations
- 2018Synthesis and characterisation of control porosity resorcinol formaldehyde based carbon aerogels under different conditions
- 2018Effect of nitrogen doping on physical and electrochemical properties of resorcinol / formaldehyde based carbons
- 2017Synthesis and electrochemical properties of highly porous nitrogen-doped carbon for improved supercapacitor performance
- 2017Improving the functionality of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications
- 2017Electrochemical performance of controlled porosity resorcinol/formaldehyde based carbons as electrode materials for supercapacitor applicationscitations
Places of action
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article
Effect of physical activation/surface functional groups on wettability and electrochemical performance of carbon/activated carbon aerogels based electrode materials for electrochemical capacitors
Abstract
Polymeric carbon/activated carbon aerogels were synthesized through sol-gel polycondensation reaction followed by the carbonization at 800 °C under Argon (Ar) atmosphere and subsequent physical activation under CO2 environment at different temperatures with different degrees of burn-off. Significant increase in BET specific surface area (SSA) from 537 to 1775 m2g−1 and pore volume from 0.24 to 0.94 cm3g−1 was observed after physical activation while the pore size remained constant (around 2 nm). Morphological characterization of the carbon and activated carbons was conducted using X-ray diffraction (XRD) and Raman spectroscopy. Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to investigate the effect of thermal treatment (surface cleaning) on the chemical composition of carbon samples.<br/><br/>Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to analyse the capacitive and resistive behaviour of non-activated/activated/and surface cleaned activated carbons employed as electroactive material in a two electrode symmetrical electrochemical capacitor (EC) cell with 6 M KOH solution used as the electrolyte.<br/><br/>CV measurements showed improved specific capacitance (SC) of 197 Fg−1 for activated carbon as compared to the SC of 136 Fg−1 when non-activated carbon was used as electroactive material at a scan rate of 5 mVs−1. Reduction in SC from 197 Fg−1 to 163 Fg−1 was witnessed after surface cleaning at elevated temperatures due to the reduction of surface oxygen function groups.<br/><br/>The result of EIS measurements showed low internal resistance for all carbon samples indicating that the polymeric carbons possess a highly conductive three dimensional crosslinked structure. Because of their preferred properties such as controlled porosity, exceptionally high specific surface area, high conductivity and desirable capacitive behaviour, these materials have shown potential to be adopted as electrode materials in electrochemical capacitors.