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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jancelewicz, Mariusz
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Block copolymer interfaces investigated by means of NMR, atomic force microscopy and dielectric spectroscopy
- 2023Highly regular laser-induced periodic silicon surface modified by MXene and ALD TiO2 for organic pollutants degradationcitations
- 2020Porous Silicon‐Zinc Oxide Nanocomposites Prepared by Atomic Layer Deposition for Biophotonic Applicationscitations
- 2020Formation and photoluminescence properties of ZnO nanoparticles on electrospun nanofibers produced by atomic layer depositioncitations
- 2020Porous Silicon-Zinc Oxide Nanocomposites Prepared by Atomic Layer Deposition for Biophotonic Applicationscitations
- 2019Structural and dynamic study of block copolymer – Nanoparticles nanocompositescitations
- 2017Silicon/TiO<inf>2</inf> core-shell nanopillar photoanodes for enhanced photoelectrochemical water oxidationcitations
- 2016Effect of annealing temperature on optical and electrical properties of metallophthalocyanine thin films deposited on silicon substratecitations
- 2015Structural and XPS studies of PSi/TiO2 nanocomposites prepared by ALD and Ag-assisted chemical etchingcitations
- 2015Atomic layer deposition TiO2 coated porous silicon surface: Structural characterization and morphological featurescitations
- 2015Study on Structural, Mechanical, and Optical Properties of Al<inf>2</inf>O<inf>3</inf>-TiO<inf>2</inf> Nanolaminates Prepared by Atomic Layer Depositioncitations
- 2013Molecular dynamics in PBA/PEO miktoarm star copolymerscitations
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article
Silicon/TiO<inf>2</inf> core-shell nanopillar photoanodes for enhanced photoelectrochemical water oxidation
Abstract
<p>Nanostructured Si/TiO<sub>2</sub> core-shell nanopillar (NP) photoanodes were synthesized to overcome photodegradation stability of Si and to enhance the efficiency for photoelectrochemical water splitting. The core-shell structures were fabricated by atomic layer deposition of TiO<sub>2</sub> onto Si nanopillars synthesized by metal-assisted chemical etching and nanosphere lithography. Scanning electron microscopy, transmission electron microscopy, Raman and reflectance spectroscopies were utilized to characterize fabricated photoanodes. The obtained Si/TiO<sub>2</sub> core-shell NP arrays exhibit less than 6% of optical reflectance in UV and visible region, providing good optical absorption. Photoelectrochemical (PEC) water oxidation of fabricated photoanodes was studied. We showed that n-Si/n-TiO<sub>2</sub> NP exhibited a larger photocurrent than p-Si/n-TiO<sub>2</sub> due to a barrier at the heterojunction. Optimal morphological parameter of Si/TiO<sub>2</sub> NP for enhanced PEC water splitting were found. We demonstrated its enhanced PEC performance with a photocurrent density of 1.5 mA/cm<sup>2</sup> under simulated solar radiation with intensity of 100 mW/cm<sup>2</sup>. The relationship between the PEC performance and the electrolyte pH was also discussed. The design of the geometry of Si/TiO<sub>2</sub> core-shell NP arrays offers a new approach for preparing stable and highly efficient photoanodes for PEC water splitting.</p>