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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rebholz, Claus
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (31/31 displayed)
- 2024Short-Time Magnetron Sputtering for the Development of Carbon–Palladium Nanocomposites
- 2024Asymmetric supercapacitors based on biomass-derived porous activated carbon (PAC)/1D manganese oxide (MnO2) electrodes with high power and energy densitiescitations
- 2023Improved thermolytic dehydrogenation of LiBH4 nanoconfined in few-layer graphene with different functionalitiescitations
- 2023Uniform Droplet Spraying of Magnesium Alloyscitations
- 2021Additive manufacturing of magnesium alloy using uniform droplet spraying: modeling of microstructure evolutioncitations
- 2021Synthesis of bulk reactive Ni–Al composites using high pressure torsioncitations
- 2020Effect of Pt nanoparticle decoration on the H2 storage performance of plasma-derived nanoporous graphenecitations
- 2018Novel combustion synthesis of carbon foam‑aluminum fluoride nanocomposite materialscitations
- 2018Novel combustion synthesis of carbon foam‑aluminum fluoride nanocomposite materialscitations
- 2018Needle grass array of nanostructured nickel cobalt sulfide electrode for clean energy generationcitations
- 2017Mechanics and energetics modeling of ball-milled metal foil and particle structurescitations
- 2017Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal-organic framework (IRMOF-1) materialcitations
- 2017Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal–organic framework (IRMOF-1) materialcitations
- 2014Spark ignitable ball milled powders of Al and Ni at NiAl compositioncitations
- 2013Fabrication, characterization and applications of novel nanoheater structurescitations
- 2012Broom-like and flower-like heterostructures of silver molybdate through pH controlled self assemblycitations
- 2012Tensile mechanical properties and hydraulic permeabilities of electrospun cellulose acetate fiber meshes.
- 2011Deposition and nanotribological characterization of Sub-100-nm thick protective Ti-based coatings for miniature applicationscitations
- 2011Textured VN coatings with Ag3VO4 solid lubricant reservoirscitations
- 2011Ultrasonic Consolidation and Ignition Characteristics of Thermite Compositescitations
- 2010Adaptive VN/Ag nanocomposite coatings with lubricious behavior from 25 to 1000 °ccitations
- 2009Tribological behavior of CrN and Al-Cr-N coatings
- 2009Modeling of the self-propagating reactions of nickel and aluminum multilayered foilscitations
- 2009The nanostructure, wear and corrosion performance of arc-evaporated CrBxNy nanocomposite coatingscitations
- 2008Tribological properties of twin electron-beam evaporated Cr-N and Al-Cr-N coatings under laboratory sliding and drill experimentscitations
- 2008Nanostructure, mechanical and tribological properties of reactive magnetron sputtered TiCx coatingscitations
- 2008Synthesis and characterization of Cr-B-N coatings deposited by reactive arc evaporationcitations
- 2006Nanostructural studies of PVD TiAlB coatingscitations
- 2005Characterisation and tribological evaluation of nitrogen-containing molybdenum-copper PVD metallic nanocomposite filmscitations
- 2002Evaluating the microstructure and performance of nanocomposite PVD TiAlBN coatingscitations
- 2002Electron spectroscopic studies of nanocomposite PVD TiAlBN coatingscitations
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article
Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal-organic framework (IRMOF-1) material
Abstract
A nanoporous metal–organic framework material, exhibiting an IRMOF-1 type crystalline structure, was prepared by following a direct solvothermal synthesis approach, using zinc nitrate and terephthalic acid as precursors and dimethylformamide as solvent, combined with supercritical CO2 activation and vacuum outgassing procedures. A series of advanced characterization methods were employed, including scanning electron microscopy, Fourier-transform infrared radiation spectroscopy and X-ray diffraction, in order to study the morphology, surface chemistry and structure of the IRMOF-1 material directly upon its synthesis. Porosity properties, such as Brunauer–Emmet–Teller (BET) specific area (∼520 m2/g) and micropore volume (∼0.2 cm3/g), were calculated for the activated sample based on N2 gas sorption data collected at 77 K. The H2 storage performance was preliminary assessed by low-pressure (0–1 bar) H2 gas adsorption and desorption measurements at 77 K. The activated IRMOF-1 material of this study demonstrated a fully reversible H2 sorption behavior combined with an adequate gravimetric H2 uptake relative to its BET specific area, thus achieving a value of ∼1 wt.% under close-to-atmospheric pressure conditions.