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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Steriotis, Theodore
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023Destabilization of the LiBH 4 –NaBH 4 Eutectic Mixture through Pore Confinement for Hydrogen Storagecitations
- 2022Fundamentals of hydrogen storage in nanoporous materialscitations
- 2020Embedding ordered mesoporous carbons into thermosensitive hydrogels: A cutting-edge strategy to vehiculate a cargo and control its release profilecitations
- 2020Effect of Pt nanoparticle decoration on the H2 storage performance of plasma-derived nanoporous graphenecitations
- 2020Hydrogen sorption and reversibility of the LiBH 4 -KBH 4 eutectic system confined in a CMK-3 type carbon via melt infiltrationcitations
- 2018Novel combustion synthesis of carbon foam‑aluminum fluoride nanocomposite materialscitations
- 2017Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal-organic framework (IRMOF-1) materialcitations
- 2013The effect of compositional changes on the structural and hydrogen storage properties of (La-Ce)Ni5 type intermetallics towards compounds suitable for metal hydride hydrogen compression.citations
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article
Solvothermal synthesis, nanostructural characterization and gas cryo-adsorption studies in a metal-organic framework (IRMOF-1) material
Abstract
A nanoporous metal–organic framework material, exhibiting an IRMOF-1 type crystalline structure, was prepared by following a direct solvothermal synthesis approach, using zinc nitrate and terephthalic acid as precursors and dimethylformamide as solvent, combined with supercritical CO2 activation and vacuum outgassing procedures. A series of advanced characterization methods were employed, including scanning electron microscopy, Fourier-transform infrared radiation spectroscopy and X-ray diffraction, in order to study the morphology, surface chemistry and structure of the IRMOF-1 material directly upon its synthesis. Porosity properties, such as Brunauer–Emmet–Teller (BET) specific area (∼520 m2/g) and micropore volume (∼0.2 cm3/g), were calculated for the activated sample based on N2 gas sorption data collected at 77 K. The H2 storage performance was preliminary assessed by low-pressure (0–1 bar) H2 gas adsorption and desorption measurements at 77 K. The activated IRMOF-1 material of this study demonstrated a fully reversible H2 sorption behavior combined with an adequate gravimetric H2 uptake relative to its BET specific area, thus achieving a value of ∼1 wt.% under close-to-atmospheric pressure conditions.