| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mendes, Adélio
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (44/44 displayed)
- 2023C-N linked donor type porphyrin derivatives: unrevealed hole-transporting materials for efficient hybrid perovskite solar cellscitations
- 2023The effect of Bi doping on the thermal conductivity of ZnO and ZnO:Al thin films
- 2022PEDOT-graphene counter-electrode for solar and improved artificial light conversion in regular, bifacial and FTO-less cobalt mediated DSSCscitations
- 2022Vanadium (oxy)nitride as a new category of anode for direct ammonia solid oxide fuel cells cellscitations
- 2022An all-in-one approach for self-powered sensing: a methanol fuel cell modified with a molecularly imprinted polymer for cancer biomarker detectioncitations
- 2021Graded morphologies and the performance of PffBT4T-2OD:PC71BM devices using additive choicecitations
- 2021Production of hydrogen from methanol steam reforming using CuPd/ZrO2 catalysts - Influence of the catalytic surface on methanol conversion and CO selectivitycitations
- 2021A passive direct methanol fuel cell as transducer of an electrochemical sensor, applied to the detection of carcinoembryonic antigencitations
- 2021Passivation of the TiO2 Surface and Promotion of N719 Dye Anchoring with Poly(4-vinylpyridine) for Efficient and Stable Dye-Sensitized Solar Cellscitations
- 2020Accelerated aging of anticorrosive coatings: Two-stage approach to the AC/ DC/AC electrochemical methodcitations
- 2019Double-walled iron oxide nanotubes via selective chemical etching and Kirkendall processcitations
- 2019Integrated design of hematite and dye-sensitized solar cell for unbiased solar charging of an organic-inorganic redox flow batterycitations
- 2019Development of hermetic glass frit encapsulation for perovskite solar cellscitations
- 2018Furanoate-Based Nanocomposites: A Case Study Using Poly(Butylene 2,5-Furanoate) and Poly(Butylene 2,5-Furanoate)-co-(Butylene Diglycolate) and Bacterial Cellulosecitations
- 2018Embedded Chromium Current Collectors for Efficient and Stable Large Area Dye Sensitized Solar Cellscitations
- 2018Recent developments in the optimization of the bulk heterojunction morphology of polymer: Fullerene solar cellscitations
- 2018Combined in-depth X-ray Photoelectron Spectroscopy and Time-of-Flight Secondary Ion Mass Spectroscopy study of the effect of deposition pressure and substrate bias on the electrical properties and composition of Ga-doped ZnO thin films grown by magnetron sputteringcitations
- 2018Polyol synthesis of reduced graphene oxide supported platinum electrocatalysts for fuel cells: Effect of Pt precursor, support oxidation level and pHcitations
- 2017Low temperature hermetic laser-assisted glass frit encapsulation of soda lime glass substratescitations
- 2017Highly efficient SiO2/TiO2 composite photoelectrodes for dye-sensitized solar cellscitations
- 2017Development of stable current collectors for large area dye-sensitized solar cellscitations
- 2017Heat integration of methanol steam reformer with a high-temperature polymeric electrolyte membrane fuel cellcitations
- 2017TiO2-coated window for facilitated gas evolution in PEC solar water splittingcitations
- 2017Synergetic integration of a methanol steam reforming cell with a high temperature polymer electrolyte fuel cellcitations
- 2017TiO2/reduced graphene oxide composites for photocatalytic degradation in aqueous and gaseous mediumcitations
- 2016The influence of impurities in high temperature polymer electrolyte membrane fuel cells performancecitations
- 2016Intensification of Photocatalytic Pollutant Abatement in Microchannel Reactor Using TiO2 and TiO2-Graphenecitations
- 2016Extremely stable bare hematite photoanode for solar water splittingcitations
- 2016Photoelectrochemical water splitting using WO3 photoanodes: the substrate and temperature rolescitations
- 2015Composite-alumina-carbon molecular sieve membranes prepared from novolac resin and boehmite. Part I: Preparation, characterization and gas permeation studiescitations
- 2015Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splittingcitations
- 2014Evaluation of Bonding Performance of Amino Polymers Using ABEScitations
- 2014Laser assisted dye-sensitized solar cell sealing: From small to large cells areascitations
- 2014Hematite photoelectrodes for water splitting: evaluation of the role of film thickness by impedance spectroscopytcitations
- 2013Use of Segmented Cell Operated in Hydrogen Recirculation Mode to Detect Water Accumulation in PEMFCcitations
- 2012Glass-Glass Laser-Assisted Glass Frit Bondingcitations
- 2012Laser assisted glass frit sealing of dye-sensitized solar cellscitations
- 2011A dynamic model for high temperature polymer electrolyte membrane fuel cellscitations
- 2011Segmented polymer electrolyte membrane fuel cells-A reviewcitations
- 2011Phenomenological modeling of dye-sensitized solar cells under transient conditionscitations
- 2011An Electrochemical Impedance Spectroscopy Study of Polymer Electrolyte Membrane Fuel Cells Electrocatalyst Single Wall Carbon Nanohorns-Supportedcitations
- 2011The influence of CO on the current density distribution of high temperature polymer electrolyte membrane fuel cellscitations
- 2011Use of single wall carbon nanohorns in polymeric electrolyte fuel cellscitations
- 2010Proton conductive membranes based on doped sulfonated polytriazolecitations
Places of action
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article
The influence of impurities in high temperature polymer electrolyte membrane fuel cells performance
Abstract
This work investigates the influence of carbon dioxide and non-reacted methanol, present in the reformate stream obtained via methanol steam reforming, in the performance of high temperature polymer electrolyte membrane fuel cells (HT-PEMFC), operating between 160 degrees C and 180 degrees C. The HT-PEMFC anode was fed with pure hydrogen, hydrogen balanced with carbon dioxide (75%/25% vol.) and synthetic reformate mixture, considering also vaporized methanol solution in the reformate content (up to 10% vol.). The synthetic reformate was feed during cycles of 420 min. The fuel cell was characterized based on the polarization curve and electrochemical impedance spectroscopy (EIS) analysis. Additionally, acid base titrations were performed to access the phosphoric acid content in different sections of the MEAs as well as scanning electron microscopy (SEM). A low impact in the fuel cell performance was observed when three cycles of synthetic reformate containing methanol solution were performed. When the number of cycles was increased, the performance of HT-PEMFC decreases and irreversible degradation of performance was observed. The cycles with synthetic reformate increased the ohmic resistance and high frequency resistance associated with anodic processes, but decreased the intermediate frequency resistance associated with cathodic processes. Additionally, by increasing the number of cycles, the phosphoric acid content of Celteca (R) MEAs and the thickness of the membrane decreased. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.