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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Celorrio, Verónica
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Water-hydroxide trapping in cobalt tungstate for proton exchange membrane water electrolysiscitations
- 2024Water-hydroxide trapping in cobalt tungstate for proton exchange membrane water electrolysiscitations
- 2022Structure-Activity Relationships in Highly Active Platinum-Tin MFI-type Zeolite Catalysts for Propane Dehydrogenationcitations
- 2018Insights into the durability of Co-Fe spinel oxygen evolution electrocatalystscitations
- 2018Effects of heat treatment atmosphere on the structure and activity of Pt3Sn nanoparticle electrocatalysts:a characterisation case studycitations
- 2018AMnO3 (A = Sr, La, Ca, Y) Perovskite Oxides as Oxygen Reduction Electrocatalystscitations
- 2017YFeO3 Photocathodes for Hydrogen Evolutioncitations
- 2017YFeO 3 Photocathodes for Hydrogen Evolutioncitations
- 2016Influence of thermal treatments on the stability of Pd nanoparticles supported on graphitised ordered mesoporous carbonscitations
- 2015Surface Activation of Pt Nanoparticles Synthesised by "Hot Injection" in the Presence of Oleylaminecitations
- 2015Fast One-Pot Synthesis of MoS2/Crumpled Graphene p-n Nanonjunctions for Enhanced Photoelectrochemical Hydrogen Productioncitations
- 2014Fuel cell performance of Pt electrocatalysts supported on carbon nanocoilscitations
- 2012Electrocatalytic Properties of Strained Pd Nanoshells at Au Nanostructures: CO and HCOOH Oxidationcitations
- 2010Modification of the properties of carbon nanocoils by different treatments in liquid phasecitations
Places of action
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article
Influence of thermal treatments on the stability of Pd nanoparticles supported on graphitised ordered mesoporous carbons
Abstract
The graphitisation of ordered mesoporous carbons (CMK-3) was carried out by thermal treatments under different conditions of temperature and heating rate. The electrochemical characterization in acidic medium of the graphitised CMK-3 showed that such a thermal treatment is effective to decrease the carbon oxidation rate (corrosion) while preserving a good porosity in terms of capacitance. Besides, the graphitisation degree and, in consequence, the electrochemical corrosion resistance can be modulated by an appropriate choice of thermal treatment conditions, where the heating rate and temperature appear as critical parameters. Under certain graphitisation conditions, the carbon corrosion of CMK-3 can be minimized showing lower rates compared to a commercial carbon black (Vulcan). Palladium nanoparticles were supported on the most promising graphitised CMK-3 and Vulcan using a method based on impregnation and reduction with borohydride, resulting in suitable metal crystallite sizes. The electrocatalytic activity towards the oxidation of carbon monoxide and formic acid were assessed in aqueous sulphuric acid electrolyte for application at the anode of direct formic acid fuel cells (DFAFCs). The best activity results were obtained for the Pd catalyst supported on a graphitised CMK-3.