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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Palcut, Marián
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Publications (7/7 displayed)
- 2020Properties of Sn-Ag-Cu Solder Joints Prepared by Induction Heatingcitations
- 2012Improved oxidation resistance of ferritic steels with LSM coating for high temperature electrochemical applicationscitations
- 2012Efficient dual layer interconnect coating for high temperature electrochemical devicescitations
- 2010Thermal Analysis of the Sn-Ag-Cu-In Solder Alloycitations
- 2010Corrosion stability of ferritic stainless steels for solid oxide electrolyser cell interconnectscitations
- 2009Thermal analysis of selected tin-based lead-free solder alloys
- 2009The interpretation of the DSC signals of the lead-free solder alloy systems using the CALPHAD approach
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article
Efficient dual layer interconnect coating for high temperature electrochemical devices
Abstract
Effects of novel dual layer coatings Co3O4/La0.85Sr0.15MnO3−δ on high temperature oxidation behaviour of candidate steels for interconnects are studied at 1123 K in flowing simulated ambient air (air + 1% H2O) and oxygen. Four alloys are investigated: Crofer 22 APU, Crofer 22 H, E-Brite and AL 29-4C. The reaction kinetics is followed by measuring the mass increase of the samples over time. The oxide scale microstructure and chemical composition are investigated by scanning electron microscopy/energy dispersive spectroscopy. The kinetic data follow the parabolic rate law. It is found that the oxidation reaction is limited by outward Cr3+ diffusion in the chromia scale. The coating effectively reduces the oxidation rate. Reactions and cation inter-diffusion between the coating and the oxide scale are observed. Long term effects of these interactions are discussed and practical implications for interconnect electrochemical performance are suggested.