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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Madeira, Lm
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2023Fe-containing carbon-coated monoliths prepared by CVD in gaseous toluene abatement-parametric analysis of the Fenton processcitations
- 2022Gaseous toluene abatement by the heterogeneous Fenton-like process using iron/carbon-coated monolith as catalyst: Proof of conceptcitations
- 2022Unravelling the relation between processed crude oils and the composition of spent caustic effluents as well as the respective economic impactcitations
- 2019Low temperature glycerol steam reforming over a Rh-based catalyst combined with oxidative regenerationcitations
- 2016Chemical and photochemical degradation of polybrominated diphenyl ethers in liquid systems - A reviewcitations
- 2014Azo-dye orange II degradation by the heterogeneous Fenton-like process using a zeolite Y-Fe catalyst-Kinetics with a model based on the Fermi's equationcitations
- 2014Removal of paraquat pesticide with Fenton reaction in a pilot scale water systemcitations
- 2014Boehmite-phenolic resin carbon molecular sieve membranes-Permeation and adsorption studiescitations
- 2013Influence of the iron precursor in the preparation of heterogeneous Fe/activated carbon Fenton-like catalystscitations
- 2013Drinking water and biofilm disinfection by Fenton-like reactioncitations
- 2010Enhancing the production of hydrogen via water-gas shift reaction using Pd-based membrane reactorscitations
- 2007Azo-dye Orange II degradation by heterogeneous Fenton-like reaction using carbon-Fe catalystscitations
- 2005Proton electrolyte membrane properties and direct methanol fuel cell performance II. Fuel cell performance and membrane properties effectscitations
- 2005Performance and efficiency of a DMFC using non-fluorinated composite membranes operating at low/medium temperaturescitations
- 2002New evidences of redox mechanism in n-butane oxidative dehydrogenation over undoped and Cs-doped nickel molybdatescitations
Places of action
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article
Enhancing the production of hydrogen via water-gas shift reaction using Pd-based membrane reactors
Abstract
In this work it is described an experimental study regarding the performance of a Pd-Ag membrane reactor recently proposed and suitable for the production of ultra pure hydrogen A dense metallic permeator tube was assembled by an innovative annealing and diffusion welding technique from a commercial flat sheet membrane of Pd-Ag A "finger like' configuration of the self supported membrane has been designed and used as a packed bed membrane reactor (MR) for producing ultra pure hydrogen via water gas shift reaction (WGS) A CuO/ZnO/Al2O3 catalyst, from REB Research & Consulting was used for packing the WGS membrane reactor The performance of the reactor was evaluated in terms of CO conversion and H-2 recovery in a wide range of conditions temperature from 200 degrees C to 300 degrees C, feed pressure from 1 0 bar to 4 0 bar vacuum and sweep gas modes and with a simulated reformate feed (4 70% CO 34 78% H2O, 28 70% H-2 10 16% CO2 balanced in N-2) Also the effect of the reactants feed composition was investigated and discussed CO conversions remained in most conditions above the thermodynamic equilibrium based on feed conditions In particular it is worth mentioning that around 100% of CO conversion and almost complete H-2 recovery was achieved when operating the MR at 300 degrees C with a GSHV = 1200 L-N kg(cat)(-1)h(-1) P-feed = 4 bar P-perm = 3 bar and using 1000 mL(N) min(-1) of sweep gas