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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fichtner, M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2020Metal (boro-) hydrides for high energy density storage and relevant emerging technologiescitations
- 2019Oxygen Activity in Li-Rich Disordered Rock-Salt Oxide and the Influence of LiNbO$_{3}$ Surface Modification on the Electrochemical Performancecitations
- 2018Effect of oxidizer in the synthesis of NiO anchored nanostructure nickel molybdate for sodium-ion batterycitations
- 2015Development of new anode composite materials for fluoride ion batteries
- 2015Single step tranformation of sulphur to Li₂S₂/Li₂S in Li-S batteries
- 2013A facile synthesis of a carbon-encapsulated Fe₃O₄ nanocomposite and its performance as anode in lithium-ion batteriescitations
- 2013Influence of particle size and fluorination ratio of CFₓ precursor compounds on the electrochemical performance of C-FeF₂ nanocomposites for reversible lithium storagecitations
- 2012Synthesis and characterisation of a mesoporous carbon/calcium borohydride nanocomposite for hydrogen storagecitations
- 2012Tailored heat transfer characteristics of pelletized LiNH2-MgH2 and NaAlH4 hydrogen storage materialscitations
- 2011On the decomposition of the 0.6LiBH4-0.4Mg(BH4)2 eutectic mixture for hydrogen storagecitations
- 2011Modified synthesis of [Fe/LiF/C] nanocomposites, and its application as conversion cathode material in lithium batteriescitations
- 2009Thermal coupling of a high temperature PEM fuel cell with a complex hydride tankcitations
- 2004Nanotechnological approaches in the development of materials for hydrogen storage
- 2004Nanotechnological aspects in materials for hydrogen storage
Places of action
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article
Thermal coupling of a high temperature PEM fuel cell with a complex hydride tank
Abstract
Sodium alanate doped with cerium catalyst has been proven to have fast kinetics for hydrogen ab- and de-sorption as well as a high gravimetric storage density around 5 wt%. The kinetics of hydrogen sorption can be improved by preparing the alanate as nanocrystalline material. However, the second decomposition step, i.e. the decomposition of the hexahydride to sodium hydride and aluminium which refers to 1.8 wt% hydrogen is supposed to happen above 110 degrees C. The discharge of the material is thus limited by the level of heat supplied to the hydride storage tank. Therefore, we evaluated the possibilities of a thermal coupling of a high temperature PEM fuel cell operating at 160-200 degrees C. The starting temperatures and temperature hold-times before starting fuel cell operation, the heat transfer characteristics of the hydride storage tanks, system temperature, fuel cell electrical power (including efficiency) as well as alanate kinetics were varied by system modelling with gPROMS (R). The kinetics of the hydride decomposition was found to have a major influence on the performance of the system. A cumulative output of 0.8 kWh was reached in a test run.