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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Baniasadi, Hossein
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Polypyrrole-modified flax fiber sponge impregnated with fatty acids as bio-based form-stable phase change materials for enhanced thermal energy storage and conversioncitations
- 2024Polypyrrole-modified flax fiber sponge impregnated with fatty acids as bio-based form-stable phase change materials for enhanced thermal energy storage and conversioncitations
- 2024Fabrication of biocomposite materials with polycaprolactone and activated carbon extracted from agricultural wastecitations
- 2024Exploring the potential of regenerated Ioncell fiber composites: a sustainable alternative for high-strength applicationscitations
- 2024Elucidating the enduring transformations in cellulose-based carbon nanofibers through prolonged isothermal treatmentcitations
- 2024Wood flour and Kraft lignin enable air-drying of the nanocellulose-based 3D-printed structurescitations
- 2024Recycled carbon fiber reinforced composites: Enhancing mechanical properties through co-functionalization of carbon nanotube-bonded microfibrillated cellulosecitations
- 2024A cradle-to-gate life cycle assessment of polyamide-starch biocomposites: carbon footprint as an indicator of sustainabilitycitations
- 2023Strontium-Substituted Nanohydroxyapatite-Incorporated Poly(lactic acid) Composites for Orthopedic Applications: Bioactive, Machinable, and High-Strength Propertiescitations
- 2023Flexible and conductive nanofiber textiles for leakage-free electro-thermal energy conversion and storagecitations
- 2023Heat-Induced Actuator Fibers: Starch-Containing Biopolyamide Composites for Functional Textilescitations
- 2023High-concentration lignin biocomposites with low-melting point biopolyamidecitations
- 2023Innovative integration of pyrolyzed biomass into polyamide 11: Sustainable advancements through in situ polymerization for enhanced mechanical, thermal, and additive manufacturing propertiescitations
- 2021Exfoliated clay nanocomposites of renewable long-chain aliphatic polyamide through in-situ polymerizationcitations
- 2021Sustainable composites of surface-modified cellulose with low-melting point polyamidecitations
- 2021Novel long-chain aliphatic polyamide/surface-modified silicon dioxide nanocomposites: in-situ polymerization and propertiescitations
- 2021Alginate/cartilage extracellular matrix-based injectable interpenetrating polymer network hydrogel for cartilage tissue engineeringcitations
- 2021Selective Laser Sintering of Lignin-Based Compositescitations
- 20213D-Printed Thermoset Biocomposites Based on Forest Residues by Delayed Extrusion of Cold Masterbatch (DECMA)citations
- 2021High-Performance and Biobased Polyamide/Functionalized Graphene Oxide Nanocomposites through In Situ Polymerization for Engineering Applicationscitations
- 2015Investigation of thermomechanical properties of UHMWPE/graphene oxide nanocomposites prepared by in situ Ziegler–Natta polymerizationcitations
Places of action
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article
Elucidating the enduring transformations in cellulose-based carbon nanofibers through prolonged isothermal treatment
Abstract
This study investigates the conversion of highly acetylated sugarcane bagasse into high-modulus carbon nanofibers (CnNFs) with exceptional electrical conductivity. By electrospinning the bagasse into nanofibers with diameters ranging from 80 nm to 800 nm, a cost-effective CnNFs precursor is obtained. The study reveals the transformation of the cellulose crystalline structure into a stable antiparallel chain arrangement of cellulose II following prolonged isothermal treatment, leading to a remarkable 50 % increase in CnNFs recovery with carbon contents ranging from 80 % to 90 %. This surpasses the performance of any other reported biomass precursors. Furthermore, graphitization-induced shrinkage of CnNFs diameter results in significant growth of specific surface area and pore volume in the resulting samples. This, along with a highly ordered nanostructure and high crystallinity degree, contributes to an impressive tensile modulus of 9.592 GPa, surpassing that of most petroleum-based CnNFs documented in the literature. Additionally, the prolonged isothermal treatment influences the d002 value (measured at 0.414 nm) and CnNFs degree of crystallinity, leading to an enhancement in electrical conductivity. However, the study observes no size effect advantages on mechanical properties and electrical conductivity, possibly attributed to the potential presence of point defects in the ultrathin CnNFs. Overall, this research opens a promising and cost-effective pathway for converting sugarcane biomasses into high-modulus carbon nanofibers with outstanding electrical conductivity. These findings hold significant implications for the development of sustainable and high-performance materials for various applications, including electronics, energy storage, and composite reinforcement.