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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Molinari, Michael
University of Bordeaux
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2023Influence of surface chemistry of fiber and lignocellulosic materials on adhesion properties with polybutylene succinate at nanoscalecitations
- 2023Influence of Surface Chemistry of Fiber and Lignocellulosic Materials on Adhesion Properties with Polybutylene Succinate at Nanoscalecitations
- 2023Influence of Surface Chemistry of Fiber and Lignocellulosic Materials on Adhesion Properties with Polybutylene Succinate at Nanoscalecitations
- 2020Atomic force microscopy reveals how relative humidity impacts the Young’s modulus of lignocellulosic polymers and their adhesion with cellulose nanocrystals at the nanoscalecitations
- 2020Synthesis of Core-Shell Al/tiO(2)Nanotube Composites by Electrochemical Methodscitations
- 2018Single step electrodeposition process using ionic liquid to grow highly luminescent silicon/rare earth (Er, Tb) thin films with tunable compositioncitations
- 2018All electrochemical process for synthesis of Si coating on TiO2 nanotubes as durable negative electrode material for lithium ion batteriescitations
- 2017A novel design of a scanning probe microscope integrated with an ultramicrotome for serial block-face nanotomographycitations
- 2017An instrumental approach to combining confocal microspectroscopy and 3D scanning probe nanotomographycitations
- 2015Nanocharacterization of chemical and mechanical properties of plant cell walls and lignocellulosic bioinspired assemblies
- 2015Organosolv lignin as natural grafting additive to improve the water resistance of films using cellulose nanocrystalscitations
- 2012Semiconductor quantum dots affect fluidity of purple membrane from Halobacterium salinarum through disruption of bacteriorhodopsin trimer organizationcitations
- 2011Structure and optical properties of plant cell wall bioinspired materials: cellulose-lignin multilayer nanocompositescitations
Places of action
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article
Atomic force microscopy reveals how relative humidity impacts the Young’s modulus of lignocellulosic polymers and their adhesion with cellulose nanocrystals at the nanoscale
Abstract
Lignocellulosic biomass is receiving growing interest as a renewable source of biofuels, chemicals and materials. Lignocellulosic polymers and cellulose nanocrystals (CNCs) present high added-value potential in the nanocomposite field, but some issues have to be solved before large-scale applications. Among them, the interaction between polymers at the nanoscale and the effect of the external parameters on the mechanical properties have to be more precisely investigated. The present study aims at evaluating how the relative humidity affects the reduced Young’s modulus of lignocellulosic films prepared with crystalline cellulose, glucomannan, xylan and lignin and how relative humidity changes their nanoscale adhesion properties with CNCs. Using atomic force microscopy and force volume experiments with CNC-functionalized levers, increasing the relative humidity is shown to decrease the Young’s modulus values of the different films and promote their adhesion forces with CNCs. In particular, CNCs more strongly interact with glucomannan and lignin than xylan, and in the case of lignin, the oxidation of the film promotes strong variations in the adhesion force. Such results allow to better understand the lignocellulosic film properties at the nanoscale, which should lead to an improvement in the production of new highly added-value composites.