| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pedersen, Steen Uttrup
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Steering carbon dioxide reduction toward C–C coupling using copper electrodes modified with porous molecular filmscitations
- 2022Can the CO 2 Reduction Reaction Be Improved on Cu:Selectivity and Intrinsic Activity of Functionalized Cu Surfacescitations
- 2022Can the CO2Reduction Reaction Be Improved on Cucitations
- 2020Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachmentscitations
- 2020Stimuli-responsive degrafting of polymer brushes via addressable catecholato-metal attachmentscitations
- 2020Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layerscitations
- 2020Facile Access to Disulfide/Thiol Containing Poly(glycidyl methacrylate) Brushes as Potential Rubber Adhesive Layerscitations
- 2018Facile Synthesis of Iron- and Nitrogen-Doped Porous Carbon for Selective CO 2 Electroreductioncitations
- 2018Efficient bonding of ethylene-propylene-diene M-class rubber to stainless steel using polymer brushes as a nanoscale adhesivecitations
- 2017Efficient Graphene Production by Combined Bipolar Electrochemical Intercalation and High-Shear Exfoliationcitations
- 2016Hydrophilic Polymer Brush Layers on Stainless Steel Using Multilayered ATRP Initiator Layercitations
- 2014Durability of PEEK adhesive to stainless steel modified with aryldiazonium saltscitations
Places of action
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article
Efficient bonding of ethylene-propylene-diene M-class rubber to stainless steel using polymer brushes as a nanoscale adhesive
Abstract
A novel approach to bond rubber to metal using nanometers thick polymer brushes in the interface is investigated. An atom transfer radical polymerization (ATRP) initiator is grafted to the surface of stainless steel (SS) and poly(glycidyl methacrylate) (PGMA) brushes are grown from the surface. Benzoyl peroxide (BPO) is drop casted on the polymer films before the samples are overmolded with ethylene-propylene-diene M-class (EPDM) rubber. For surface concentrations below 0.2 µmol cm -2 regions with adhesive failure were observed. Thermal infrared reflectance absorption spectroscopy (T-IRRAS) and X-ray photoelectron spectroscopy (XPS) show a conversion of oxirane groups after heating samples to 170 °C. A compression molding system designed to mold uncured rubber on modified SS samples and subsequently to perform peel tests of the rubber-steel specimens are presented. Four stages of crack propagation are identified in the peel data: 1) elastic loading, 2) stable crack propagation, 3) unstable crack propagation, and 4) loss of load carrying capacity. The novel nanometer thick bonding system was benchmarked against a commercial bonding system. Calculated peel energies are in good agreement with previously reported values and show no significant difference compared to a commercial bonding agent. Therefore, it is concluded that the novel bonding system applying only a nanometer thick surface immobilized polymer brush layer offers similar adhesion as existing micrometer thick primer adhesives.