| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Coles, Sj
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2023β,β-directly linked porphyrin ringscitations
- 2023N=8 armchair graphene nanoribbonscitations
- 2022Unprecedented platinum(II) coordination compound of sterically hindered 3,3′-bis(NH-benzimidazol-2-yl)-2,2′-bipyridine ligand
- 2022Aryl, bi-functionalised imidazo[4,5-f]-1,10-phenanthroline ligands and their luminescent rhenium(I) complexescitations
- 2021Spectroscopic, structural and DFT studies of luminescent Pt(II) and Ag(I) complexes with an asymmetric 2,2'-bipyridine chelating ligandcitations
- 2021Insights into the structure-property relationship of pharmaceutical co-crystals: charge density and quantum chemical approachescitations
- 2020Oxidopolyborate chemistrycitations
- 2020Oxidopolyborate anions templated by transition-metal complex cations: Self-assembled syntheses and structural studies (XRD) of [Co(NH3)6]2[B4O5(OH)4]3·11H2O, [Ni(phen)3][B7O9(OH)5]·9.5H2O and [Zn(dac)2(H2O)2][B7O9(OH)5]·H2Ocitations
- 2019Syntheses, X-ray structures and characterisation of luminescent chromium(III) complexes incorporating 8-quinolinato ligandscitations
- 2019Synthesis, characterisation and electrochemistry of eight Fe coordination compounds containing substituted 2-(1-(4-R-phenyl-1H-1,2,3-triazol-4-yl)pyridine ligands, R = CH3, OCH3, COOH, F, Cl, CN, H and CF3citations
- 2019Highly efficient fullerene and non-fullerene based ternary organic solar cells incorporating a new tetrathiocin-cored semiconductorcitations
- 2018Synthesis, characterisation and electrochemistry of eight Fe coordination compounds containing substituted 2-(1-(4-R-phenyl-1H-1,2,3-triazol-4-yl)pyridine ligands, R = CH3, OCH3, COOH, F, Cl, CN, H and CF3citations
- 2018Two 1-D coordination polymers containing zinc(II) hexaborates: [Zn(en{B6O7(OH)6}]2H2O (en =1,2-diaminoethane) and [Zn(pn{B6O7(OH)6}]1.5H2O (pn = 1,2-diaminopropane)citations
- 2017Synthesis, XRD studies and NLO properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO properties of some related pentaborate(1−) saltscitations
- 2017Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato NiII complexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligandcitations
- 2017Structural organization in the trimethylamine iodine monochloride complexcitations
- 2013A multinuclear solid state NMR, density functional theory and X-Ray diffraction study of hydrogen bonding in Group I hydrogen dibenzoatescitations
- 2013The competition between halogen bonds (Br???O) and C–H???O hydrogen bonds: the structure of the acetone–bromine complex revisitedcitations
- 2010Seven 3-methylidene-1H-indol-2(3H)-ones related to the multiple-receptor tyrosine kinase inhibitor sunitinibcitations
- 2010A chiral ferromagnetic molecular metalcitations
- 2008Synthesis, structure, and supramolecular architecture of benzonitrile and pyridine adducts of bis(pentafluorophenyl)zinc: pentafluorophenyl-aryl interactions versus homoaromatic pairingcitations
- 2006Synthesis and X-ray characterization of the organotriboroxinate salts [Me3NCH2CH2OH][Ph4B3O3] and [NEt3H][Ph3B3O3(OH)], and the X-ray structure of the triarylboroxine, (4-MeOC6H4)(3)B3O3citations
- 2006New pyridyl modified phosphines: Synthesis and late transition-metal coordination studiescitations
- 2006The formation and isolation of benzisothiazole rings from the reactions of oxime-thiophenolate ligandscitations
- 2005Intramolecular and intermolecular N-H···F-C hydrogen-bonding interactions in amine adducts of tris(pentafluorophenyl)borane and tris(pentafluorophenyl)alanecitations
- 2004Syntheses, spectroscopic and molecular quadratic nonlinear optical properties of dipolar ruthenium(II) complexes of the ligand 1,2-phenylenebis(dimethylarsine)citations
- 2004Mixed valence Mn(II)/Mn(III) [3 x 3] grid complexes: structural, electrochemical, spectroscopic, and magnetic propertiescitations
- 2003Synthesis and characterisation of a series of Group 7 metal 2,2,2,2-dicarbonylbis(triorganophosphine)-arachno-2-metallatetraboranes, M(CO)(2)L-2(B3H8) (M=Re, Mn); crystal and molecular structures of Re(CO)(2)(dppf)(B3H8) and Mn(CO)(2)(dppe)(B3H8)citations
- 2002Synthesis, crystal structure, and enhancement of the efficacy of metronidazole against Entamoeba histolytica by complexation with palladium(II), platinum(II), or copper(II)
Places of action
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article
Unprecedented platinum(II) coordination compound of sterically hindered 3,3′-bis(NH-benzimidazol-2-yl)-2,2′-bipyridine ligand
Abstract
The synthesis, spectroscopic characterization, single-crystal X-ray diffraction (SCXD) analysis, and Density Functional Theory (DFT) and time-dependent DFT (TD-DFT) studies of the coordination compound of cis-dichloroplatinum(II) with a sterically hindered N4-donor ligand, 3,3′-bis(NH-benzimidazol-2-yl)-2,2′-bipyridine (L), [Pt(L)Cl2]⋅DMSO (1) (DMSO = dimethyl sulfoxide) are reported. The Pt(II) ion adopts a slightly distorted square-planar geometry in which L coordinates in a bidentate fashion to the metal center through N atom of benzimidazole (bim) and N atom of pyridine (py) to form a seven-membered ring. The molecular units in the lattice are held together in a head to tail fashion as a dimer through intermolecular hydrogen bonding between the uncoordinated bim and py rings in the molecule through N single bond H⋅⋅⋅N hydrogen bonds with the(14) graph-set motif. The lattice DMSO solvent molecule significantly stabilizes the structure through N single bond H⋅⋅⋅O hydrogen bond with the coordinated bim in the structure. Hirshfeld surface analysis also confirmed the hydrogen bond interactions in the crystal. DFT and TD-DFT results show that optimized geometry and UV-vis absorption spectra are consistent with the experimental results. Natural bond orbital (NBO) properties show that the hydrogen bond stability between the two monomers attributes with large stabilization energy values.