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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lang, H.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2018Cobalt and manganese carboxylates for metal oxide thin film deposition by applying the atmospheric pressure combustion chemical vapour deposition processcitations
- 2018The synthesis, chemical and physical properties of silver(I) carboxylates and their use for joining of copper
- 2018Joining of copper at low temperatures using silver(I) carboxylatescitations
- 2018Enantiorecognition performances of "inherently chiral" film electrodes: a successful first example with planar-chirality probes
- 2017Co(II) ethylene glycol carboxylates for Co<inf>3</inf>O<inf>4</inf> nanoparticle and nanocomposite formationcitations
- 2016Manganese half-sandwich complexes as metal-organic chemical vapor deposition precursors for manganese-based thin filmscitations
- 2016Atomic layer deposition of ultrathin Cu2O and subsequent reduction to Cu studied by in situ x-ray photoelectron spectroscopycitations
- 2016Investigation on the structural behavior of a metallically 3D-reinforced CFRP/CFRP joint using a variable search based on finite element analyzescitations
- 2016Structural Aspects of Thermally Cleavable Adducts Derived from the Reaction of Imidazolines with Isocyanatescitations
- 2015Influence of surface treatment and design of 3D-reinforcements on delamination resistance & mechanical properties of CFRP/CFRP joints under static & fatigue loading ; Influence Of Reinforcement Design On Delamination Resistance & Mechanical Properties Of Cfrp/Cfrp Joints Under Static & Fatigue Loading
- 2014Surface chemistry of a Cu(I) beta-diketonate precursor and the atomic layer deposition of Cu2O on SiO2 studied by x-ray photoelectron spectroscopycitations
- 2014High energy X-ray diffraction study of a dental ceramics–titanium functional gradient material prepared by field assisted sintering techniquecitations
- 2014Structural health monitoring with quantum dots
- 2014Influence of an optimized 3D-reinforcement layout on the structural mechanics of co-bonded CFRP joints
- 2013Molecular Wires using (Oligo)pyrroles as Connecting Units: An Electron Transfer Studycitations
- 2012Development and optimization of an innovative joining technique for composite structures using the Finite Element method
- 2012Magneto-optical Kerr-effect studies on copper oxide thin films produced by atomic layer deposition on SiO2citations
- 2009Copper oxide ALD from a Cu(I) beta-diketonate: Detailed growth studies on SiO2 and TaNcitations
- 2009Copper oxide ALD from a Cu(I) beta-diketonate: Growth studies and application as seed layers for electrochemical copper depositioncitations
- 2009Detailed study of copper oxide ALD on SiO2, TaN, and Ru
- 2008ALD of Copper and Copper Oxide Thin Films for Applications in Metallization Systems of ULSI Devices
- 2008Investigation into the strength of components made of UFG aluminium alloys
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article
The synthesis, chemical and physical properties of silver(I) carboxylates and their use for joining of copper
Abstract
<p>The synthesis of [AgO2CCR2OC(O)OMe] (6, R = H; 7, R = Me) by treatment of HO2CCR2OC(O)OMe (4, R = H; 5, R = Me) with [AgNO3] in presence of NEt3 is reported. The reaction of 6 and 7 with 2 equiv of PPh3 gave [AgO2CCR2OC(O)OMe(PPh3)(2)] (8, R = H; 9, R = Me). The thermal behavior of 6 and 7 was studied by TG, DSC and TG-MS of which the latter evinced decarboxylation as initial decomposition step followed by Ag-C, C-C and C-O bond cleavages giving silver. For copper-to-copper joining, 6 and 7 were processed to spreadable pastes by mixing them with ethylene glycol (EG) or diethylene glycol (DEG). On contact of 7-EG with Cu sheets [Cu-2(O2CCMe2OC(O)OMe)(4).2H(2)O] (12) was formed. Therefore, only 6-EG and 6-DEG were used for pressureless joining of Cu at 250 degrees C. Thru addition of Ag mu m-particles a tensile shear strength of 19 MPa was achieved, showing a significant higher value as received with commercially Ag nanopastes. The solid state structure of 5, 8, 9 and 12 was determined by single crystal X-ray structure analysis, showing [3+1] (P2O + O) (8), distorted tetrahedral (9) or octahedral (12) coordination spheres at the metal ion. (C) 2018 Published by Elsevier B.V.</p>