| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Hogarth, Graeme
King's College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2021Dithiocarbamate Complexes as Single Source Precursors to Nanoscale Binary, Ternary and Quaternary Metal Sulfidescitations
- 2017An exhibition of different coordination modes displayed by 2-vinylpyrazine and 2-vinylpyridine at triosmium centrescitations
- 2016Hydrogenase biomimeticscitations
- 2015Synthesis, structure and bonding of new mono- and dinuclear molybdenum complexes containing pyridine-2-thiolate (pyS) and different P-donorscitations
- 2014A comparative study of the reactivity of the lightly stabilized cluster [Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H)] towards tri(2-thienyl)-, tri(2-furyl)- and triphenyl-phosphinecitations
- 2014A comparative study of the reactivity of the lightly stabilized cluster [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] towards tri(2-thienyl)-, tri(2-furyl)- and triphenyl-phosphinecitations
- 2008Reaction of [Ru-3(CO)(12)] with tri(2-furyl)phosphine: Di- and tri-substituted triruthenium and phosphido-bridged diruthenium complexescitations
Places of action
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article
Synthesis, structure and bonding of new mono- and dinuclear molybdenum complexes containing pyridine-2-thiolate (pyS) and different P-donors
Abstract
<p>Three new molybdenum complexes have been synthesized from one-pot reactions between Mo(CO)<sub>3</sub>(NCMe)<sub>3</sub> and pyridine-2-thiol (pySH) in the presence of different P-donors. Reaction with P(OMe)<sub>3</sub> in MeCN at ca. 55 °C gives Mo(CO)<sub>2</sub>[P(OMe)<sub>3</sub>](κ<sup>2</sup>-pyS)<sub>2</sub> (1) and Mo(CO)<sub>4</sub>[P(OMe)<sub>3</sub>]<sub>2</sub> (2). A similar reaction involving bis(diphenylphosphino)methane (dppm) furnishes the dinuclear species Mo<sub>2</sub>(CO)<sub>4</sub>(μ,κ<sup>2</sup>-pyS)<sub>2</sub>(κ<sup>2</sup>-dppm) (3) together with the mononuclear complexes Mo(CO)(κ<sup>2</sup>-pyS)<sub>2</sub>(κ<sup>2</sup>-dppm) (4) and Mo(CO)<sub>4</sub>(κ<sup>2</sup>-dppm) (5). With bis(diphenylphosphino)ethane (dppe) only the mononuclear complexes Mo(CO)(κ<sup>2</sup>-pyS)<sub>2</sub>(κ<sup>2</sup>-dppe) (6), Mo(CO)<sub>4</sub>(κ<sup>2</sup>-dppe) (7), and Mo(CO)<sub>3</sub>(κ<sup>1</sup>-dppe)(κ<sup>2</sup>-dppe) (8) resulted. Complexes 1, 3, and 6 have been characterized by single-crystal X-ray diffraction analyses and the bonding in 1 and 3 has been evaluated by density functional theory (DFT) calculations, optimized structures being discussed relative to the observed solid-state structures.</p>