| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Fernández-Lodeiro, Javier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2019Highly accessible aqueous synthesis of well-dispersed dendrimer type platinum nanoparticles and their catalytic applicationscitations
- 2019Exploring the control in antibacterial activity of silver triangular nanoplates by surface coating modulationcitations
- 2017Synthesis and Characterization of PtTe2 Multi-Crystallite Nanoparticles using Organotellurium Nanocompositescitations
- 2017Supercritical CO2-assisted spray drying of strawberry-like gold-coated magnetite nanocomposites in chitosan powders for inhalationcitations
- 2015Novel nanocomposites based on a strawberry-like gold- coated magnetite (Fe@Au) for protein separation in multiple myeloma serum samplescitations
- 2014Bioinspired Functionalized Nanoparticles as Tools for Detection, Quantification and Targeting of Biomolecules
- 2012Novel emissive podands based on 8-OH-quinoline: Synthesis, fluorescence materials, DFT and complexation studiescitations
Places of action
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article
Novel emissive podands based on 8-OH-quinoline: Synthesis, fluorescence materials, DFT and complexation studies
Abstract
<p>Two novel chemosensors with podand structures (L<sup>1</sup>and L<sup>2</sup>) derived from 1,5-bis(2-aminophenoxy)-3-oxopenthane bearing two flexible 8-hydroxyquinoline units have been synthesized and characterized. Several nitrate complexes of transition (Cu<sup>2+</sup>), post-transition (Zn<sup>2+</sup>) and lanthanide (Eu<sup>3+</sup>and Sm<sup>3+</sup>) metal ions have been synthesized with tetrafluoroborate salts and characterized. In order to study their potential utility as fluorescent probes, the coordination ability of chemosensors (L<sup>1</sup>and L<sup>2</sup>) towards those metal ions has been explored in solution (by UV-Vis and emission spectroscopy) and in gas phase (by MALDI mass spectrometry). Density functional theory has been employed to explore the emission properties of the three-protonation states of the chemosensor. From this study, the anomalous red shift observed in the fluorescence spectra of the dianionic sensors can be attributed to subtle structural differences between their anionic and dianionic forms. Furthermore, a plausible explanation for the low fluorescence of the neutral form is provided in the form of a non-radiative relaxation involving the imine double-bond isomerization. All new compounds have been characterized by microanalysis, melting points, IR, UV-Vis and fluorescence emission spectroscopy and MALDI-TOF-mass spectrometry.</p>