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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Pettinari, C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2011Synthesis, spectroscopic and structural characterization of some novel adducts of copper(II) salts with unidentate nitrogen basescitations
- 2011Mechanochemical synthesis in copper(II) halide/pyridine systems: single crystal X-ray diffraction and IR spectroscopic studiescitations
- 2009Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterizationcitations
- 2008Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' speciescitations
- 2007Crystal and Molecular Structures of the Organometallic Species [Rh2(bim)2(cod)2]Cl2 ·2H2O [bim = bis-(1-imidazolyl)methane; cod = 1,5-cyclooctadiene]citations
- 2007Synthesis, spectroscopic and structural characterization of the reaction products of quaternary cationic 2,2'-bipyridylium ligand bromide salts with metal halidescitations
- 2006The structural definition of adducts of stoichiometry MX : dpex (2 : 3)(∞), M = CuI, AgI, X = simple anion, dpex = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Syntheses and structures of adducts of stoichiometry MX:dpex (2:1)(n), M = CuI, AgI, X = (pseudo-) halogen, dppx = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Structural characterizations of some adducts of silver(I) nitrate and perchlorate with some cyclic di- (or tri-) ene organic ligandscitations
- 2005The structural definition of adducts of stoichiometry AgX:dppf (1:1)(n), X = simple anion, dppf = bis(diphenylphosphino)ferrocenecitations
- 2005The structural definition of adducts of stoichiometry MX:dppx (1:1) M = CuI, AgI, X = simple anion, dppx=Ph2P(CH 2)xPPh2, x = 3-6citations
- 2005Structural characterization of 1:1 adducts of silver(I) (pseudo-) halides (AgX, X = NCO, Cl, Br, I) with Ph2E(CH2)EPh2 (E = P, As) (‘dp(p/a)m’) and 4:3 adducts of copper(I) halide (CuX, X = Cl, Br, I), containing trinuclear cations, of the form [X2Ag3(dppm)3]X and [X2Cu3(dppm)3](CuX2) and the novel neutral [(OCN)3Ag3(dpam)3]citations
- 2004Syntheses and spectroscopic and structural characterization of silver(I) complexes containing tris(isobutyl)phosphine and polyl(azol-1-yl)boratescitations
- 2004Gold derivatives of scorpionates: comparison with the other coinage metal poly(pyrazolyl)borate analoguescitations
- 2002Synthesis, spectroscopic and structural characterization of Cu(II) derivatives of tris(pyrazol-1-yl)methanescitations
- 2002Silver derivatives of tris(pyrazol-1-yl)methanes. A silver(I) nitrate complex containing a tris(pyrazolyl)methane coordinated in a bridging modecitations
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article
Synthesis, spectroscopic and structural characterization of some novel adducts of copper(II) salts with unidentate nitrogen bases
Abstract
Syntheses, spectroscopic characterization and single crystal X-ray studies are reported for a number of complexes of copper(II) salts with simple monodentate nitrogen bases. The 1: 4 adduct of copper(II) sulfate with 3,5-dimethylpyridine (m(2)py) CuSO4 center dot 4m(2)py, takes the form [(O3SO)Cu(m(2)py)(4)], the Cu-O vector of the square-pyramidal coordination environment being disposed on the 4-axis in tetragonal space group P4/n. The complex CuCO3 center dot Cu(NCS)(2)center dot 4py is a linear polymer, taking the form ... O center dot Cu(py)(2)center dot O center dot C{O center dot Cu(py)(2)(NCS)(2)}center dot O center dot Cu(py)(2) ... (etc.), all atoms lying in the mirror plane of space group Pnma, excepting the pair of 'py' (pyridine) ligands disposed to either side. In Cu(OH)I center dot 3/4I(2)center dot 2py center dot 1/2MeCN [{(py)(2)Cu(OH)}(4)](I-3)(3)I center dot 2MeCN a novel cubanoid tetranuclear cation is found (2-symmetry). The EPR spectra of the above compounds show a trend in the anisotropy of the g-values that correlates well with the crystal structures. Obtained only in small quantities but supported by single crystal X-ray studies are the adduct of Cu(OH)Cl with pyrrolidine (pyrr), Cu(OH)Cl:pyrr (1:3), which takes the centrosymmetric binuclear form [(pyrr)(3)Cu(mu-OH)(2)Cu(pyrr)(3)]Cl-2, the copper atom being disposed in a distorted trigonal bipyramidal array, and the adduct 3CuCl(2)center dot CuO center dot 4quin, [Cu4Cl6O(quin)(4)]Cl-2, which contains the familiar Cu4Cl6O core with monodentate quinuclidine (quin) attached to the copper atoms; this compound crystallizes in the cubic space group (4) over bar 3m. (C) 2011 Elsevier B.V. All rights reserved.