| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Huguet, Xavier Solans
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (1/1 displayed)
Places of action
| Organizations | Location | People |
|---|
article
Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)
Abstract
Complex [PdCl(bdtp)](BF4), in presence of AgBF4 or NaBF4, reacts with pyridine (py), triphenylphosphine (PPh3), cyanide (CN-), thiocyanate (SCN-) or azide (N3-) ligands, leading to the formation of the following complexes: [Pd(bdtp)(py)](BF4)2 [1](BF4)2, [Pd(bdtp)(PPh3)](BF4)2 [2](BF4)2, [Pd(CN)(bdtp)](BF4) [3](BF4), [Pd(SCN)(bdtp)](BF4) [4](BF4) and [Pd(N3)(bdtp)](BF4) [5](BF4). These complexes were characterised by elemental analyses, mass spectrometry, conductivity measurements, infrared and NMR spectroscopies. The crystal structure of [2](BF4)2 was determined by single-crystal X-ray diffraction methods. The metal atom is coordinated by two azine nitrogen atoms, and one sulfur atom of the thioether-pyrazole ligand and one triphenylphosphine in a distorted square-planar geometry. © 2009 Elsevier B.V. All rights reserved.