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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Ngoune, J.
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Publications (5/5 displayed)
- 2021Particles size and distribution on the improvement of the mechanical performance of high strength solid solution based inorganic polymer composites: A microstructural approachcitations
- 2021Mechanical strength and microstructure of metakaolin/volcanic ash-based geopolymer composites reinforced with reactive silica from rice husk ash (RHA)citations
- 2021Innovative porous ceramic matrices from inorganic polymer composites (IPCs): Microstructure and mechanical propertiescitations
- 2009Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterizationcitations
- 2008Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' speciescitations
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article
Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterization
Abstract
1:1 and 2:1 adducts of diphosphine ligands R2P(R′)nPR2 (dppm: R = Ph, R′ = CH2, n = 1; dppe: R = Ph, R′ = CH2, n = 2; dppp: R = Ph, R′ = CH2, n = 3; dppb: R = Ph, R′ = CH2, n = 4; dppf: R = Ph, R′ = ferrocenyl, n = 1) with silver(I) methanesulfonate have been synthesized and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single crystal X-ray structure analysis). The two different stoichiometries have been found to depend on the molar ratio of ligand to metal employed and the nature of the diphosphine ligand. In AgO3SMe:dppp,dppb (1:1)2, in the [Ag(P^P)2Ag] arrays, the silver atoms are also bridged by anion oxygen atoms, in disparate fashion commensurate with the different Agcdots, three dots, centeredAg distances.