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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pettinari, C.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2011Synthesis, spectroscopic and structural characterization of some novel adducts of copper(II) salts with unidentate nitrogen basescitations
- 2011Mechanochemical synthesis in copper(II) halide/pyridine systems: single crystal X-ray diffraction and IR spectroscopic studiescitations
- 2009Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterizationcitations
- 2008Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' speciescitations
- 2007Crystal and Molecular Structures of the Organometallic Species [Rh2(bim)2(cod)2]Cl2 ·2H2O [bim = bis-(1-imidazolyl)methane; cod = 1,5-cyclooctadiene]citations
- 2007Synthesis, spectroscopic and structural characterization of the reaction products of quaternary cationic 2,2'-bipyridylium ligand bromide salts with metal halidescitations
- 2006The structural definition of adducts of stoichiometry MX : dpex (2 : 3)(∞), M = CuI, AgI, X = simple anion, dpex = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Syntheses and structures of adducts of stoichiometry MX:dpex (2:1)(n), M = CuI, AgI, X = (pseudo-) halogen, dppx = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Structural characterizations of some adducts of silver(I) nitrate and perchlorate with some cyclic di- (or tri-) ene organic ligandscitations
- 2005The structural definition of adducts of stoichiometry AgX:dppf (1:1)(n), X = simple anion, dppf = bis(diphenylphosphino)ferrocenecitations
- 2005The structural definition of adducts of stoichiometry MX:dppx (1:1) M = CuI, AgI, X = simple anion, dppx=Ph2P(CH 2)xPPh2, x = 3-6citations
- 2005Structural characterization of 1:1 adducts of silver(I) (pseudo-) halides (AgX, X = NCO, Cl, Br, I) with Ph2E(CH2)EPh2 (E = P, As) (‘dp(p/a)m’) and 4:3 adducts of copper(I) halide (CuX, X = Cl, Br, I), containing trinuclear cations, of the form [X2Ag3(dppm)3]X and [X2Cu3(dppm)3](CuX2) and the novel neutral [(OCN)3Ag3(dpam)3]citations
- 2004Syntheses and spectroscopic and structural characterization of silver(I) complexes containing tris(isobutyl)phosphine and polyl(azol-1-yl)boratescitations
- 2004Gold derivatives of scorpionates: comparison with the other coinage metal poly(pyrazolyl)borate analoguescitations
- 2002Synthesis, spectroscopic and structural characterization of Cu(II) derivatives of tris(pyrazol-1-yl)methanescitations
- 2002Silver derivatives of tris(pyrazol-1-yl)methanes. A silver(I) nitrate complex containing a tris(pyrazolyl)methane coordinated in a bridging modecitations
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article
Silver(I) methanesulfonate complexes containing diphosphine ligands: Spectroscopic and structural characterization
Abstract
1:1 and 2:1 adducts of diphosphine ligands R2P(R′)nPR2 (dppm: R = Ph, R′ = CH2, n = 1; dppe: R = Ph, R′ = CH2, n = 2; dppp: R = Ph, R′ = CH2, n = 3; dppb: R = Ph, R′ = CH2, n = 4; dppf: R = Ph, R′ = ferrocenyl, n = 1) with silver(I) methanesulfonate have been synthesized and characterized both in solution (1H, 31P NMR) and in the solid state (IR, single crystal X-ray structure analysis). The two different stoichiometries have been found to depend on the molar ratio of ligand to metal employed and the nature of the diphosphine ligand. In AgO3SMe:dppp,dppb (1:1)2, in the [Ag(P^P)2Ag] arrays, the silver atoms are also bridged by anion oxygen atoms, in disparate fashion commensurate with the different Agcdots, three dots, centeredAg distances.