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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pettinari, R.
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Publications (2/2 displayed)
- 2008Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' speciescitations
- 2004Syntheses and spectroscopic and structural characterization of silver(I) complexes containing tris(isobutyl)phosphine and polyl(azol-1-yl)boratescitations
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article
Structural forms in complexes of 2,9-dimenthyl-1,10-phenanthroline with simple salts of copper(I) and other univalent 'closed shell' species
Abstract
Syntheses, spectroscopic and structural characterizations of a series of Cu(I)-phenanthroline complexes are reported. A single crystal X-ray structure determination is recorded for CuNO3: dmp: MeCN (1:1:1), 'dmp' =2,9-dimethyl-1,10-phenanthroline, showing it to be isomorphous with its previously studied tetrafluoroborate, perchlorate and hexafluorophosphate, and silver(I) perchlorate counterparts, the metal atom lying in a trigonal planar [(NN) Cu(NCMe)] coordination environment, the anion not being coordinated. Structure (re-) determinations are also reported for a number of salts of the [Cu(dmp)(2)](+) cation: the perchlorate, isomorphous with numerous other salts, not only of copper(I), but also lithium(I)), also the unsolvated nitrate, and a solvated form of the chloride. (C) 2007 Elsevier B. V. All rights reserved.