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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nicola, C. Di
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Topics
Publications (7/7 displayed)
- 2011Synthesis, spectroscopic and structural characterization of some novel adducts of copper(II) salts with unidentate nitrogen basescitations
- 2011Mechanochemical synthesis in copper(II) halide/pyridine systems: single crystal X-ray diffraction and IR spectroscopic studiescitations
- 2006The structural definition of adducts of stoichiometry MX : dpex (2 : 3)(∞), M = CuI, AgI, X = simple anion, dpex = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2006Syntheses and structures of adducts of stoichiometry MX:dpex (2:1)(n), M = CuI, AgI, X = (pseudo-) halogen, dppx = Ph2E(CH2)xEPh2, E = P, Ascitations
- 2005The structural definition of adducts of stoichiometry AgX:dppf (1:1)(n), X = simple anion, dppf = bis(diphenylphosphino)ferrocenecitations
- 2005The structural definition of adducts of stoichiometry MX:dppx (1:1) M = CuI, AgI, X = simple anion, dppx=Ph2P(CH 2)xPPh2, x = 3-6citations
- 2005Structural characterization of 1:1 adducts of silver(I) (pseudo-) halides (AgX, X = NCO, Cl, Br, I) with Ph2E(CH2)EPh2 (E = P, As) (‘dp(p/a)m’) and 4:3 adducts of copper(I) halide (CuX, X = Cl, Br, I), containing trinuclear cations, of the form [X2Ag3(dppm)3]X and [X2Cu3(dppm)3](CuX2) and the novel neutral [(OCN)3Ag3(dpam)3]citations
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article
The structural definition of adducts of stoichiometry AgX:dppf (1:1)(n), X = simple anion, dppf = bis(diphenylphosphino)ferrocene
Abstract
Single crystal X-ray structural characterizations are recorded for an array of adducts of the form AgX:dppf (1:1)((n)), X = simple (pseudo-)halide or oxy-anion, 'dppf' = bis(diphenyl phosphino)ferrocene, for adducts X = Cl (new phase), Br, I, SCN, OCN, CN, NO3 (new phase), O2CCH3, n = 2, the form being dimeric [(dppf-P,P')Ag(mu-X)(2)Ag(P,P'-dppf)], for X = I, SCN, [Ag(mu-X)(2)(P-dppf-P')(2)Ag']; for X = O2CCF3 n = infinity, the form is an extended polymer: ...Ag(O . CO . CF3)(P-dppf-P')Ag'(O.... A dichloromethane solvate phase of CuI:dppf (1:1)(2) (also centrosymmetric) is also recorded. Synthetic procedures for all adducts have been reported. All compounds have been characterized both in solution (H-1, C-13, P-31 NMR, ESI MS) and in the solid state (IR). The topology of the structures in the solid state was found to depend on the nature of the counterion. (C) 2004 Elsevier B.V. All rights reserved.