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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gil, Vanesa
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2018Influence of porosity on mechanical properties of tetragonal stabilized zirconiacitations
- 2016Oxygen permeation flux through 10Sc1YSZ-MnCo2O4 asymmetric membranes prepared by two-step sinteringcitations
- 2016Oxygen permeation flux through 10Sc1YSZ-MnCo 2 O 4 asymmetric membranes prepared by two-step sinteringcitations
- 2014High Performance Infiltrated Backbones for Cathode-Supported SOFC's
- 2014High Performance Infiltrated Backbones for Cathode-Supported SOFC's
- 2012Redox behaviour and ageing of GDC-Co cermets: A comparison between lamellar and conventional cermetscitations
- 2011Anode-supported microtubular cells fabricated with gadolinia-doped ceria nanopowderscitations
- 2010Textured cermets of CeO2 (or GDC) with Co for solid oxide fuel cells anodescitations
- 2010Low-temperature preparation by polymeric complex solution synthesis of Cu-Gd-doped ceria cermets for solid oxide fuel cells anodes: Sinterability, microstructures and electrical propertiescitations
- 2007Effect of Bi2O3 addition on the sintering and microstructural development of gadolinia-doped ceria ceramicscitations
- 2007Inter-network magnetic interactions in GdMexMn1 xO3 perovskites (Me ¼ transition metal)citations
- 2007Structural and magnetic properties of Er(Co,Mn)O3 perovskitecitations
- 2007Sinterability, microstructures and electrical properties of Ni/Gd-doped ceria cermets used as anode materials for SOFCscitations
- 2006Sintering, microstructural development, and electrical probismuth oxide as a sintering aidperties of gadolinia-doped ceria electrolyte withcitations
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article
Oxygen permeation flux through 10Sc1YSZ-MnCo2O4 asymmetric membranes prepared by two-step sintering
Abstract
Asymmetric membranes based on a dual phase composite consisting of (Y<sub>2</sub>O<sub>3</sub>)<sub>0.01</sub>(Sc<sub>2</sub>O<sub>3</sub>)<sub>0.10</sub>(ZrO<sub>2</sub>)<sub>0.89</sub> (10Sc1YSZ) as ionic conductor and MnCo<sub>2</sub>O<sub>4</sub> as electronic conductor were prepared and characterized with respect to sinterability, microstructure and oxygen transport properties. The composite membranes were prepared by tape casting, lamination and fired in a two-step sintering process. Microstructural analysis showed that a gastight thin membrane layer with the desired ratio of ionic/electronic conducting phases could be fabricated. Oxygen permeation fluxes across the 10SclYSZ/MnCo<sub>2</sub>O<sub>4 </sub>(70/30 vol%) composite membrane were measured from 750 to 940 degrees C using air or pure oxygen as feed gases and N<sub>2 </sub>or CO<sub>2</sub> as sweep gases. Fluxes up to 2.3 ml<sub>N</sub> min<sup>-1</sup> cm<sup>-2</sup> were obtained for the 7 μm thick membrane. A degradation test over 1730 h showed an initial degradation of 21% during the first 1100 h after which stable performance was achieved. The observed degradation is attributed to coarsening of the infiltrated catalyst. (C) 2016 Elsevier B.V. All rights reserved.