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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dirbeba, Meheretu Jaleta
Åbo Akademi University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2024Analytical and applied pyrolysis of challenging biomass feedstockscitations
- 2024Analytical and applied pyrolysis of challenging biomass feedstocks:Effect of pyrolysis conditions on product yield and compositioncitations
- 2023The effect of Cl, Br, and F on high-temperature corrosion of heat-transfer alloyscitations
- 2021Effect of Storage Time on the Physicochemical Properties of Waste Fish Oils and Used Cooking Vegetable Oilscitations
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article
The effect of Cl, Br, and F on high-temperature corrosion of heat-transfer alloys
Abstract
The impact of small alkali halide additions on the melting behavior and corrosivity of a synthetic sulfate deposit at 500, 550, and 600 °C was investigated. Three differently alloyed commercial heat-transfer materials; low-alloyed 10CrMo9-10, stainless AISI 347, and high-alloyed Sanicro 28, were studied. The samples were exposed for 168 h in a tube furnace to a K 2 SO 4 + Na 2 SO 4 mixture containing 0.85 mol% KCl, KBr, or KF. The extent of material degradation was determined by weight loss measurements, while the morphology, thickness, and composition of the formed oxide scale were characterized with SEM-EDS. Additionally, the melting behavior of the mixtures was studied with TG-DTA. It could be concluded that already small amounts of reactive alkali halides in an otherwise inert K 2 SO 4 + Na 2 SO 4 mixture change significantly the corrosion and melting behavior of the mixture.