Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (13/13 displayed)

  • 2024Analytical and applied pyrolysis of challenging biomass feedstocks21citations
  • 2024Analytical and applied pyrolysis of challenging biomass feedstocks:Effect of pyrolysis conditions on product yield and composition21citations
  • 2023Cold-end corrosion caused by hygroscopic ammonium chloride in thermal conversion of biomass and waste7citations
  • 2021Formation of NH4Cl and its role on cold-end corrosion in CFB combustioncitations
  • 2021Superheater deposits and corrosion in temperature gradient – Laboratory studies into effects of flue gas composition, initial deposit structure, and exposure time23citations
  • 2020Application of bipolar electrochemistry to accelerate dew point corrosion for screening of steel materials for power boilers14citations
  • 2018Experimental and modeling approaches to simulate temperature-gradient induced intradeposit chemical processes with implications for biomass boiler corrosioncitations
  • 2017The effect of temperature on the formation of oxide scales regarding commercial superheater steels11citations
  • 2017The influence of flue gas temperature on lead chloride induced high temperature corrosion30citations
  • 2017Causes of low-temperature corrosion in combustion of bituminous coalcitations
  • 2014Changes in Composition of Superheater Deposits due to Temperature Gradientscitations
  • 2012High temperature corrosion of boiler waterwalls induced by chlorides and bromides. Part 2:Lab-scale corrosion tests and thermodynamic equilibrium modeling of ash and gaseous species27citations
  • 2011Performance of superheater materials in simulated oxy-fuel combustion conditions at 650°Ccitations

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Co-Authors (by relevance)

  • Vinu, Ravikrishnan
  • Tiwari, Mahendra
  • Dirbeba, Meheretu Jaleta
  • Lehmusto, Juho
  • Vainio, Emil
  • Hupa, Leena
  • Hupa, Mikko
  • Laurén, Tor
  • Niemi, Jonne
  • Engblom, Markus
  • Lindberg, Daniel
  • Lisak, Grzegorz
  • Bankiewicz, Dorota
  • Kinnunen, Hanna
  • Enestam, Sonja
  • Uusitalo, Mikko
  • Vänskä, Kyösti
  • Zabetta, Edgardo Coda
  • Lindberg, Daniel Kristoffer
  • Silvennoinen, Jaani
  • Frantsi, Ari
  • Vainikka, Pasi
  • Pohjanne, Pekka
  • Tuurna, Satu
OrganizationsLocationPeople

article

Application of bipolar electrochemistry to accelerate dew point corrosion for screening of steel materials for power boilers

  • Lisak, Grzegorz
  • Vainio, Emil
  • Hupa, Leena
  • Bankiewicz, Dorota
  • Yrjas, Patrik
Abstract

Maximized energy recovery in power boilers lowers the flue gas temperature. However, lowering the temperature too much may lead to problems with corrosion. The lowest operational temperature is often limited by the presence of sulphuric acid in the flue gas. Condensation of sulphuric acid may lead to severe corrosion of pre-heaters and flue gas duct parts. In this study, an experimental setup for accelerated dew point corrosion testing of steels using a concept of bipolar electrochemistry was developed. The bipolar electrochemistry was for the first time applied to study corrosion at conditions of condensing vapours of acid on the steel surface. The method allows simultaneous testing of several samples at both oxidizing and reducing conditions. In the present work, several commercial boiler steels were tested for their resistance to the dew point corrosion. It was found that bipolar electrochemistry can easily be used to accelerate corrosion for fast screening of different steel materials in simulated, dew point corrosion conditions as present in the boiler’s cold-end. The electron microscopy (SEM/EDX) analyses showed that corrosion was accelerated on carbon and high alloy steels with the use of bipolar electrochemistry. Generally, stainless steels showed very good corrosion resistance and no adverse effects caused by hot H2SO4 vapours were observed.

Topics
  • impedance spectroscopy
  • surface
  • Carbon
  • stainless steel
  • corrosion
  • scanning electron microscopy
  • Energy-dispersive X-ray spectroscopy