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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Yrjas, Patrik
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Analytical and applied pyrolysis of challenging biomass feedstockscitations
- 2024Analytical and applied pyrolysis of challenging biomass feedstocks:Effect of pyrolysis conditions on product yield and compositioncitations
- 2023Cold-end corrosion caused by hygroscopic ammonium chloride in thermal conversion of biomass and wastecitations
- 2021Formation of NH4Cl and its role on cold-end corrosion in CFB combustion
- 2021Superheater deposits and corrosion in temperature gradient – Laboratory studies into effects of flue gas composition, initial deposit structure, and exposure timecitations
- 2020Application of bipolar electrochemistry to accelerate dew point corrosion for screening of steel materials for power boilerscitations
- 2018Experimental and modeling approaches to simulate temperature-gradient induced intradeposit chemical processes with implications for biomass boiler corrosion
- 2017The effect of temperature on the formation of oxide scales regarding commercial superheater steelscitations
- 2017The influence of flue gas temperature on lead chloride induced high temperature corrosioncitations
- 2017Causes of low-temperature corrosion in combustion of bituminous coal
- 2014Changes in Composition of Superheater Deposits due to Temperature Gradients
- 2012High temperature corrosion of boiler waterwalls induced by chlorides and bromides. Part 2:Lab-scale corrosion tests and thermodynamic equilibrium modeling of ash and gaseous speciescitations
- 2011Performance of superheater materials in simulated oxy-fuel combustion conditions at 650°C
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article
Application of bipolar electrochemistry to accelerate dew point corrosion for screening of steel materials for power boilers
Abstract
Maximized energy recovery in power boilers lowers the flue gas temperature. However, lowering the temperature too much may lead to problems with corrosion. The lowest operational temperature is often limited by the presence of sulphuric acid in the flue gas. Condensation of sulphuric acid may lead to severe corrosion of pre-heaters and flue gas duct parts. In this study, an experimental setup for accelerated dew point corrosion testing of steels using a concept of bipolar electrochemistry was developed. The bipolar electrochemistry was for the first time applied to study corrosion at conditions of condensing vapours of acid on the steel surface. The method allows simultaneous testing of several samples at both oxidizing and reducing conditions. In the present work, several commercial boiler steels were tested for their resistance to the dew point corrosion. It was found that bipolar electrochemistry can easily be used to accelerate corrosion for fast screening of different steel materials in simulated, dew point corrosion conditions as present in the boiler’s cold-end. The electron microscopy (SEM/EDX) analyses showed that corrosion was accelerated on carbon and high alloy steels with the use of bipolar electrochemistry. Generally, stainless steels showed very good corrosion resistance and no adverse effects caused by hot H2SO4 vapours were observed.