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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jensen, Anker Degn
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2021Characterization of oxide-supported Cu by infrared measurements on adsorbed COcitations
- 2021Promoting effect of copper loading and mesoporosity on Cu-MOR in the carbonylation of dimethyl ether to methyl acetatecitations
- 2020Structural dynamics of an iron molybdate catalyst under redox cycling conditions studied with in situ multi edge XAS and XRDcitations
- 2019Modeling of the molybdenum loss in iron molybdate catalyst pellets for selective oxidation of methanol to formaldehydecitations
- 2019Catalytic Hydropyrolysis of Biomass using Molybdenum Sulfide Based Catalyst. Effect of Promoterscitations
- 2018Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2018Hydrogen assisted catalytic biomass pyrolysis for green fuels. Effect of cata-lyst in the fluid bed
- 2016Characterization of Free Radicals By Electron Spin Resonance Spectroscopy in Biochars from Pyrolysis at High Heating Rates and at High Temperatures
- 2016Characterization of Free Radicals By Electron Spin Resonance Spectroscopy in Biochars from Pyrolysis at High Heating Rates and at High Temperatures
- 2016Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2016Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2014In situ observation of Cu-Ni alloy nanoparticle formation by X-ray diffraction, X-ray absorption spectroscopy, and transmission electron microscopy: Influence of Cu/Ni ratiocitations
- 2014Electron microscopy study of the deactivation of nickel based catalysts for bio oil hydrodeoxygenation
- 2012Dynamic measurement of mercury adsorption and oxidation on activated carbon in simulated cement kiln flue gascitations
- 2012Catalytic Conversion of Syngas into Higher Alcohols over Carbide Catalystscitations
- 2012CO hydrogenation to methanol on Cu–Ni catalystscitations
- 2012CO hydrogenation to methanol on Cu–Ni catalysts:Theory and experimentcitations
- 2011Alkali resistant Fe-zeolite catalysts for SCR of NO with NH3 in flue gasescitations
- 2011Flame spray synthesis of CoMo/Al2O3 hydrotreating catalystscitations
- 2010Oxy-fuel combustion of solid fuelscitations
- 2009Fluidized-Bed Coating with Sodium Sulfate and PVA-TiO2, 1. Review and Agglomeration Regime Mapscitations
- 2008A review of the interference of carbon containing fly ash with air entrainment in concretecitations
- 2008Top-spray fluid bed coating: Scale-up in terms of relative droplet size and drying forcecitations
Places of action
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article
Dynamic measurement of mercury adsorption and oxidation on activated carbon in simulated cement kiln flue gas
Abstract
Mercury emissions from cement plants are being regulated by environmental agencies in most countries. Both dynamic mercury emissions in cement kiln systems and removal of mercury by sorbent injection require continuous mercury emission monitoring. Dry converters for total mercury measurements are still under development and are investigated in this work. A commercial red brass converter was tested at 180°C and it was found that the red brass chips work in nitrogen atmosphere only, but do not work properly under simulated cement kiln flue gas conditions. Test of the red brass converter using only elemental mercury shows that when HCl is present with either SO2 or NOx the mercury measurement after the converter is unstable and lower than the elemental mercury inlet level. The conclusion is that red brass chips cannot fully reduce oxidized mercury to elemental mercury when simulated cement kiln gas is applied. A sodium sulfite-based converter material was prepared by dry impregnation of sodium sulfite and calcium sulfate powders on zeolite pellets using water glass as binder. The sulfite converter works well at 500°C with less than 10ppmv HCl in the simulated cement kiln flue gas. The 95% response time of the sulfite converter is short and typically within 2min. Dynamic mercury adsorption and oxidation tests on commercial activated carbons Darco Hg and HOK standard were performed at 150°C using simulated cement kiln gas and a fixed bed reactor system. It is shown that the converter and analyzer system is capable of following the transient mercury outlet concentration in a satisfactory way. Suggestions for practical applications of the sulfite converter in both lab and cement plants are presented.