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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Simell, Pekka
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Carbon Formation in the Reforming of Simulated Biomass Gasification Gas on Nickel and Rhodium Catalystscitations
- 2018Whisker carbon formation in catalytic steam reforming of biomass gasification gascitations
- 2018Atomic layer deposition of Ti-Nb-O thin films onto electrospun fibers for fibrous and tubular catalyst support structurescitations
- 2017Method for forming catalytic nanocoating
- 2015ALD deposition of core-shell structures onto electrospun carbon webs for PEM fuel cell MEAs
- 2011Thermal plasma-sprayed nickel catalysts in the clean-up of biomass gasification gascitations
- 2007Development of zirconia catalysts for hot gas cleanup
- 2007Solid oxide fuel cell system development in VTTcitations
- 2006Characterization and control of autothermal reformer for SOFC applications
- 2000Development of novel fixed-bed gasification for biomass residues and agrobiofuels
Places of action
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article
Thermal plasma-sprayed nickel catalysts in the clean-up of biomass gasification gas
Abstract
Plasma spraying is a potential catalyst preparation method for hot gas clean-up which requires very durable catalytic coatings. In this work, the multi-layer composite coating powders consisted of a gibbsite or boehmite core together with a hydrotalcite coating. We used the coating powders in the preparation of the powder form Ni catalysts, which were characterized by XRD, BET, XPS, and XRF. The coating powders were also used in the preparation of plasma sprayed metal substrate supported Ni catalysts. Selected plasma-sprayed nickel containing catalysts were characterized by XRD and SEM. In addition, for comparative purposes we prepared and used a ceramic monolithic Ni catalyst on modified ZrO<sub>2</sub>. The performance of all catalysts were studied in the clean-up of synthetic gasification gas, i.e. the decomposition of tar, ammonia, and methane, at 700 and 900 °C, without and with the addition of H<sub>2</sub>S. Catalysts with a gibbsite-core showed higher activity and better sulfur resistance than those with a boehmite-core. The high activity of the gibbsite-core Ni catalyst with a sulfur-containing gas together with the promising mechanical and thermal strength makes the plasma spraying method an interesting alternative for gas clean-up catalysts in biomass gasification processes.<br/>