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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dewettinck, Koen
Ghent University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2024Insights in the structural hierarchy of statically crystallized palm oilcitations
- 2024Insights in the structural hierarchy of statically crystallized palm oilcitations
- 2024Unravelling the hierarchical structure of saturated monoacid triglycerides during crystallization : a comprehensive time-resolved X-ray scattering studycitations
- 2024Influencing chocolate gloss inhomogeneities by the choice of surface-active substance and contact materialcitations
- 2024From nucleation to fat crystal network : effects of stearic-palmitic sucrose ester on static crystallization of palm oilcitations
- 2024Interactions between mono- and triglycerides in hybrid fat blends : from static to dynamic processing
- 2023Accurate evaluation of the flow properties of molten chocolate : circumventing artefactscitations
- 2023Chocolate tempering in a rheometer : monitoring rheological properties during and after crystallization of cocoa buttercitations
- 2023Carnauba wax and beeswax as structuring agents for water-in-oleogel emulsions without added emulsifierscitations
- 2023Effect of temperature during production and storage of monoglyceride oleogels
- 2022Microstructure development in semi-liquid shortenings upon storage
- 2022Microstructure development in semi-liquid shortenings upon storage
- 2021Combining fat and waxes in hybrid systems for bakery application
- 2020The effect of cooling on crystallization and physico-chemical properties of puff pastry shortening made of palm oil and anhydrous milk fat blendscitations
- 2020Fat crystallization of blends of palm oil and anhydrous milk fat : a comparison between static and dynamic-crystallizationcitations
- 2018The potential of waxes to alter the microstructural properties of emulsion-templated oleogelscitations
- 2017Oil structuring properties of monoglycerides and phytosterols mixturescitations
- 2017Sequential crystallization of high and low melting waxes to improve oil structuring in wax-based oleogelscitations
- 2017Sequential crystallization of high and low melting waxes to improve oil structuring in wax-based oleogelscitations
- 2016Functionality of inulin and polydextrose as sucrose replacers in sugar-free dark chocolate manufacture : effect of fat content and bulk mixture concentration on rheological, mechanical and melting propertiescitations
- 2015Fumed silica-based organogels and 'aqueous-organic' bigelscitations
- 2015Rheological characterization of gel-in-oil-in-gel type structured emulsionscitations
- 2014Optimisation of processing conditions and rheological properties using Stephan mixer as conche in small-scale chocolate processingcitations
- 2010On the fractional crystallization of palm olein:Solid solutions and eutectic solidificationcitations
- 2009Influence of shear flow on polymorphic behavior and microstructural development during palm oil crystallizationcitations
Places of action
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article
Rheological characterization of gel-in-oil-in-gel type structured emulsions
Abstract
We report the fabrication of multiple emulsions where both the enclosed and the external water phases are structured using a combination of two non-gelling biopolymers. Emulsions (with gelled inner water droplets and gelled water continuous phase) were created using a simple 'one-step' process where the oil phase (triglyceride oil and polyglycerol polyricinoleate) and the water phase (containing a combination of locust bean gum and carrageenan) were emulsified at an elevated temperature (70 degrees C) followed by cooling to room temperature. The temperature triggered gelling of the synergistic biopolymer combination led to the formation of structured emulsions on cooling. Flowable to self-standing emulsion gels could be prepared by changing the total concentration of polymers (and the ratios of the individual polymers) as confirmed from low amplitude oscillatory shear rheology and creep recovery measurements. The cryo-scanning electron microscopy images of freeze-fractured emulsion samples revealed the presence of gelled inner water droplets. Further, when subjected to heating and cooling cycles, emulsions displayed reversible rheological changes which could be tuned by simply changing the total polymer concentration and the proportions of individual polymers. Such biopolymer-based structured emulsions with interesting microstructure and rheological properties could find potential applications in bio-related fields like food structuring.