| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Théato, Patrick
Karlsruhe Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Synthesis of Polyimide-PEO Copolymers: Toward thermally stable solid polymer electrolytes for Lithium-Metal batteriescitations
- 2024Degradation of Styrene-Poly(ethylene oxide)-Based Block Copolymer Electrolytes at the Na and K Negative Electrode Studied by Microcalorimetry and Impedance Spectroscopycitations
- 2023Magnesium Polymer Electrolytes Based on the Polycarbonate Poly(2-butyl-2-ethyltrimethylene-carbonate)
- 2023Improved Route to Linear Triblock Copolymers by Coupling with Glycidyl Ether-Activated Poly(ethylene oxide) Chainscitations
- 2023Photoresponsive Spiropyran and DEGMA‐Based Copolymers with Photo‐Switchable Glass Transition Temperaturescitations
- 2023Poly(ethylene oxide)-grafted Polycarbonates as Solvent-free Polymer Electrolytes for Lithium-Metal Batteries
- 2022Inverse Vulcanization of Norbornenylsilanes: Soluble Polymers with Controllable Molecular Properties via Siloxane Bondscitations
- 2022Synthesis and Characterization of Novel Isosorbide‐Based Polyester Derivatives Decorated with α ‐Acyloxy Amidescitations
- 2022Synthesizing Polyethylene from Polyacrylates: A Decarboxylation Approachcitations
- 2021Synthesis and Post-Polymerization Modification of Poly(N-(4-Vinylphenyl)Sulfonamide)scitations
- 2020The toolbox of porous anodic aluminum oxide–based nanocomposites: from preparation to applicationcitations
- 2020A CO$_{2}$-gated anodic aluminum oxide based nanocomposite membrane for de-emulsificationcitations
Places of action
| Organizations | Location | People |
|---|
article
Synthesis of Polyimide-PEO Copolymers: Toward thermally stable solid polymer electrolytes for Lithium-Metal batteries
Abstract
The rapid pace of technological advancement in field of electric vehicles and need in sustainable energy sources calls for new, high-performance energy storage technologies. Lithium metal batteries (LMBs) based on solid polymer electrolyte represent a promising battery technology to increase energy density of conventional batteries while enhancing safety, eliminating dendrite formation, and providing mechanical flexibility. In this study, we developed novel polyimide-poly(ethylene oxide) (PI-PEO) copolymers and employed them as solid polymer electrolytes for LMBs. Copolymers with 5, 15, and 30 mol% of PEO-containing diamine were synthesized by reacting with aromatic dianhydride and diamine, using a facile and eco-friendly method in a benzoic acid melt. Chemical structures were confirmed using NMR and IR spectroscopy. Glass transition temperatures varied from 24 °C to 195 °C, increasing with a decrease in the PEO/PI moiety ratio. All copolymers demonstrated good thermal stability up to T$_{5\%}$ > 345 °C with a two-step degradation and favorable mechanical properties below the glass transition temperature, as observed by DMA measurements. Solid polymer electrolytes with 70 wt% of LiTFSI exhibited an ionic conductivity of 1.4 × 10$^{−4}$ S cm$^{−1}$ at 70 °C, with a transference number of 0.7. The polymer electrolyte exhibited non-flammable properties and the potential for utilization in lithium metal batteries, indicating the promising application of these new polymers for high-safety battery systems.