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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Stoclet, Grégory
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Structure And Mechanical Behavior of Fully Substituted Acid Starch Esterscitations
- 2022Effect of chain orientation on the brittle to ductile transition in Polylactide
- 2022Novel family of polylactide-based copolymer matrix composites by RTM process
- 2022Hydrolytic degradation of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) - Towards an understanding of microplastics fragmentationcitations
- 2022Unprecedented polylactide-based copolymer matrix composites by Resin Transfer Molding
- 2021Comparative studies of thermal and mechanical properties of macrocyclic versus linear polylactidecitations
- 2021Poly(lactide)/cellulose nanocrystal nanocomposites by high‐shear mixingcitations
- 2021Poly(lactide)/cellulose nanocrystal nanocomposites by high-shear mixingcitations
- 2020Comparative studies of thermal and mechanical properties of macrocyclic versus linear polylactidecitations
- 2019Effect of surface modification of colloidal silica nanoparticles on the rigid amorphous fraction and mechanical properties of amorphous polyurethane–urea–silica nanocompositescitations
- 2019Water–Soluble Extracts from Banana Pseudo–stem as Functional Additives for Polylactic Acid: Thermal and Mechanical Investigationscitations
- 2018Processing of PVDF-based electroactive/ferroelectric films: importance of PMMA and cooling rate from the melt state on the crystallization of PVDF beta-crystalscitations
- 2015Comparison of the influence of talc and kaolinite as inorganic fillers on morphology, structure and thermomechanical properties of polylactide based compositescitations
- 2014Isoprene-Styrene Chain Shuttling Copolymerization Mediated by a Lanthanide Half-Sandwich Complex and a Lanthanidocene: Straightforward Access to a New Type of Thermoplastic Elastomerscitations
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article
Water–Soluble Extracts from Banana Pseudo–stem as Functional Additives for Polylactic Acid: Thermal and Mechanical Investigations
Abstract
Water Soluble Extracts (WSE) were obtained from Banana Pseudo stems (BPS) using a simple and robust deconstruction procedure. WSE were characterized by FTIR, WAXS, TGA DTG analysis. With the objective of developing fully bio based polymer formulations, WSE fillers were blended to Poly Lactic Acid (PLA) using a solution blending, casting and thermocompression process. Thermal and mechanical properties were investigated by Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA) and uniaxial tensile tests on neat PLA (n–PLA) and PLA/WSE blends at various filler contents. Thermal DSC investigations established that WSE act as a plasticizer on PLA. This was further confirmed by DMA by the shift of the loss factor (tan δ) peak maximum towards lower temperatures. WSE also significantly impacted the thermally induced crystallization of PLA and the nucleating power of WSE was assessed by isothermal and non–isothermal studies. WSE had a detrimental effect on PLA brittleness and a slightly positive in fluence on its stiffness in the glassy state, whereas the drawability remained fairly acceptable when PLA–based materials where drawn at 75 °C above Tg. Moreover, WSE induced an earlier strain–hardening of the composite films as compared to neat PLA. These results underline the valorization potential of such agricultural by products for sustainable polymer applications in the packaging industry.