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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Delcorte, Arnaud
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (49/49 displayed)
- 2024An innovative strategy to fabricate wrinkled silver-based nanoporous material combining plasma-based technique and dealloying process ; Une stratégie innovante pour fabriquer des matériaux ridés nanoporeux à base d'argent en combinant des techniques de plasma et le processus de désalliage
- 2024Investigating the Influence of the Substrate Temperature and the Organic Precursor on the Mechanical Properties of Low-Pressure Plasma Polymer Filmscitations
- 2023The influence of the substrate temperature on the growth mechanism of amine- and thiol-based plasma polymers: A comparative studycitations
- 2023Investigating the influence of the substrate temperature on the growth mechanisms of oxygen-based plasma polymer films ; Investiguer l'influence de la température du substrat sur les mécanismes de croissance des films polymères plasma oxygénés
- 2023Enhancing Ion Signals and Improving Matrix Selection in Time-of-Flight Secondary Ion Mass Spectrometry with Microvolume Expansion Using Large Argon Clusterscitations
- 2022A Microscopic View of Macromolecule Transfer in the Vacuum Using Gas and Bismuth Clusters
- 2022Gas Cluster Ion Beams as a Versatile Soft-Landing Tool for the Controlled Construction of Thin (Bio)Filmscitations
- 2021Investigating the relationship between the mechanical properties of plasma polymer-like thin films and their glass transition temperature
- 2021Investigating the relationship between the mechanical properties of plasma polymer-like thin films and their glass transition temperature
- 2021Investigating the relationship between the mechanical properties of plasma polymer-like thin films and their glass transition temperaturecitations
- 2020Argon gas cluster fragmentation and scattering as a probe of the surface physics of thermoset polymerscitations
- 2019A quantitative determination of the polymerization of benzoxazine thin coatings by timeâ€ofâ€flight secondary ion mass spectrometrycitations
- 2019Highly Efficient Wideband Microwave Absorbers Based on Zero-Valent Fe@γ-Fe2O3 and Fe/Co/Ni Carbon-Protected Alloy Nanoparticles Supported on Reduced Graphene Oxidecitations
- 2019Highly EfficientWideband Microwave Absorbers Based on Zero-Valent Fe@ -Fe2O3 and Fe/Co/Ni Carbon-Protected Alloy Nanoparticles Supported on Reduced Graphene Oxide
- 2019Mixed Polymer Brushes for the Selective Capture and Release of Proteins.citations
- 2019A quantitative determination of the polymerization of benzoxazine thin coatings by time‐of‐flight secondary ion mass spectrometrycitations
- 2019Highly Efficient Wideband Microwave Absorbers Based on Zero-Valent Fe@gamma-Fe2O3 and Fe/Co/Ni Carbon-Protected Alloy Nanoparticles Supported on Reduced Graphene Oxidecitations
- 2018Selective reduction of nitrobenzene to aniline over electrocatalysts based on nitrogen-doped carbons containing non-noble metalscitations
- 2018Selective reduction of nitrobenzene to aniline over electrocatalysts based on nitrogen-doped carbons containing non-noble metalscitations
- 2018Effect of nanoconfinement on the sputter yield in ultrathin polymeric films: Experiments and modelcitations
- 2018Polymer-matrix nanocomposites bombarded by large AR clusters and low energy Cs ions: Sputtering and topography developmentcitations
- 2018Structural characterization and magnetic properties of undoped and copper-doped cobalt ferrite nanoparticles prepared by the octanoate coprecipitation route at very low dopant concentrationscitations
- 2018A benzoxazine/substituted borazine composite coating: A new resin for improving the corrosion resistance of the pristine benzoxazine coating applied on aluminumcitations
- 2017Cross-linking degree of benzoxazine thin coatings determined by ToF-SIMS
- 2016Ni0.9Zn0.1O/ZnO nanocomposite prepared by malonate coprecipitation route for gas sensing
- 2016Formaldehyde gas sensor based on nanostructured nickel oxide and the microstructure effects on its response
- 2016Decoration of nanocarbon solids with magnetite nanoparticles: towards microwave metamaterial absorberscitations
- 2015Formaldehyde gas sensor based on nanostructured nickel oxide and the microstructure effects on its response
- 2015Coprecipitation of nickel zinc malonate: A facile and reproducible synthesis route for Ni1-xZnxO nanoparticles and Ni1-xZnxO/ZnO nanocomposites via pyrolysiscitations
- 2015Synthesis, characterization and gas sensing properties of Ni1-xZnxO nanoparticles and Ni1-xZnxO/ZnO nanocomposites
- 2014Ar cluster sputtering of polymers: effects of cluster size and molecular weightscitations
- 2014Time-of-Flight Secondary Ion Mass Spectrometry Investigation of the Orientation of Adsorbed Antibodies on SAMs Correlated to Biorecognition Testscitations
- 2014Phosphine- and ammonium-functionalized ordered mesoporous carbons as supports for cluster-derived metal nanoparticlescitations
- 2013Insights into the yield enhancement and ion emission process in metal-assisted SIMScitations
- 2012Morphology Study of small amounts of evaporated gold on polymerscitations
- 2012Static SIMS study on surfaces of chalcogenide glasses modified by an organic layercitations
- 2012Metal condensates for low-molecular-weight matrix-free laser desorption/ionizationcitations
- 2011Investigating the relation between the secondary yield enhancement and the structure of the metallic overlayer in Metal-Assisted SIMScitations
- 2009Dynamics of molecular impacts on soft materials: from fullerenes to organic nanodrops.citations
- 2008Investigation of methods to enhance the secondary ion yields in TOF-SIMS of organic samplescitations
- 2007Diffusion of oligomers from polydimethylsiloxane stamps in microcontact printing: Surface analysis and possible applicationcitations
- 2007A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imagingcitations
- 2007Metal-assisted secondary ion mass spectrometry using atomic (Ga+, In+) and fullerene projectiles.citations
- 2006Matrix-enhanced secondary ion mass spectrometry: The Alchemist's solution?citations
- 2005Modeling keV particle interactions with molecular and polymeric samplescitations
- 2005Metal salts for molecular ion yield enhancement in organic secondary ion mass spectrometry: a critical assessment.citations
- 2003Sample metallization for performance improvement in desorption/ionization of kilodalton molecules: quantitative evaluation, imaging secondary ion MS, and laser ablation.citations
- 2002Organic secondary ion mass spectrometry: sensitivity enhancement by gold deposition.citations
- 2000Inferring ejection distances and a surface energy profile in keV particle bombardment experimentscitations
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article
A benzoxazine/substituted borazine composite coating: A new resin for improving the corrosion resistance of the pristine benzoxazine coating applied on aluminum
Abstract
In this paper, laboratory synthesized Phenol-paraPhenyleneDiAmine (P-pPDA) benzoxazine containing different amounts of B-trimesityl-N-triphenylborazine was applied by spin coating on aluminum and thermally cured. The addition of the borazine derivative (borazine 1) does not appear to modify the curing characteristics of the PpPDA matrix itself as shown by FTIR, DSC and DEA analyses; however, some interactions - chemical and/or physical (co-crystallization) – between P-pPDA and borazine 1 cannot be excluded. The microstructure of the composites is characterized by a two phase system consisting of a dispersion of nanosized (10–20 nm) clusters for the lowest borazine 1 concentration (0.5 wt%), evolving towards bigger (100–200 nm), agglomerated clusters for higher borazine 1 concentrations (3 wt%) and finally, continuous, dendritic structures within the P-pPDA matrix for the highest borazine 1 concentration (10 wt%). The benzoxazine composite coating containing 0.5 wt % trimesitylborazine derivative showed a largely increased and durable ability to protect the aluminum substrate. It is shown that a highly capacitive behavior and durable barrier properties can be obtained for P-pPDA coatings containing such a low amount of borazine derivative homogeneously dispersed in the benzoxazine matrix. For concentrations of 3 wt%, as agglomeration took place and dendrites appeared for the highest concentration of borazine derivative (10 wt%), the corrosion resistance decreased with time.