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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Thissen, Peter
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Mineral Interface Doping: Hydroxyapatite Deposited on Silicon to Trigger the Electronic Properties
- 2023Theoretical elastic constants of tobermorite enhanced with reduced graphene oxide through hydroxyl vs epoxy functionalization: A first-principles studycitations
- 2021Interactions between reduced graphene oxide with monomers of (calcium) silicate hydrates: a first-principles studycitations
- 2021CO adsorption on the calcite(10.4) surface: a combined experimental and theoretical studycitations
- 2021Interactions between Reduced Graphene Oxide with Monomers of (Calcium) Silicate Hydrates: A First-Principles Studycitations
- 2019Correlation between Composition and Mechanical Properties of Calcium Silicate Hydrates Identified by Infrared Spectroscopy and Density Functional Theorycitations
- 2018Oxidative polymerization of terthiophene and a substituted thiophene monomer in metal-organic framework thin filmscitations
- 2018Hydration of Concrete: The First Stepscitations
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article
Oxidative polymerization of terthiophene and a substituted thiophene monomer in metal-organic framework thin films
Abstract
Films consisting of surface-anchored metal-organic frameworks (SURMOFs) which are prepared by layer-by-layer deposition techniques can be used as highly oriented crystalline template structures for oligomerization processes. Herein, SURMOF films of Zn(bdc) (1) and, Cu(bpdc) (2) were prepared, which consist of lamellar ordered 2D MOF sheets forming 1D channels as the host structures for oligomerization of terthiophene (Tth) and, 3,4-ethylenedioxythiophene (EDOT), respectively. After SURMOF preparation, the pores were filled either with Tth or EDOT and the oligomerization was initiated by oxidizing agents, such as I2 and FeCl3. Using matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-ToF/MS), the short chains of polyterthiophene (PTth) and poly(3,4-ethylenedioxythiophene) (PEDOT) were characterized. FT-IR and Raman spectroscopy further confirmed the presence of oligomers inside the pores of the SURMOFs. Using the SURMOF thin films as template, a homogeneously distributed conductive MOF-PEDOT composite coating can be achieved, with potential applications in optoelectronics.