| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Gliemann, Hartmut
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2020Direct Synthesis of ZIF-8 on Transmission Electron Microscopy Grids Allows Structure Analysis and 3D Reconstructioncitations
- 2020ZnO@ZIF-8: Gas sensitive core-shell hetero-structures show reduced cross-sensitivity to humiditycitations
- 2019Mobility of charge carriers in self-assembled monolayerscitations
- 2018Tailoring the Strength of Nanoporous Gold by Self-Assembled Monolayers of Alkanethiolscitations
- 2018Water as a modulator in the synthesis of surface-mounted metal–organic framework films of type HKUST-1citations
- 2018Oxidative polymerization of terthiophene and a substituted thiophene monomer in metal-organic framework thin filmscitations
- 2018Surface-Anchored Metal–Organic Frameworks as Versatile Resists for Gas-Assisted E-Beam Lithography: Fabrication of Sub-10 Nanometer Structurescitations
- 2015A Photolithographic Approach to Spatially Resolved Cross-Linked Nanolayerscitations
- 2015Hierarchically Functionalized Magnetic Core/Multishell Particles and Their Postsynthetic Conversion to Polymer Capsulescitations
- 2015Peptide-equipped tobacco mosaic virus templates for selective and controllable biomineral depositioncitations
- 2015Transparent films of metal-organic frameworks for optical applicationscitations
- 2015Tunable coordinative defects in UHM-3 surface-mounted MOFs for gas adsorption and separation: A combined experimental and theoretical studycitations
- 2015Electric transport properties of surface-anchored metal-organic frameworks and the effect of ferrocene loading.citations
- 2014Nanoporous Designer Solids with Huge Lattice Constant Gradients: Multiheteroepitaxy of Metal-Organic Frameworkscitations
- 2014Fabrication of Highly Uniform Gel Coatings by the Conversion of Surface-Anchored Metal-Organic Frameworkscitations
- 2014Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separationcitations
- 2014Oriented Circular Dichroism Analysis of Chiral Surface-Anchored Metal-Organic Frameworks Grown by Liquid-Phase Epitaxy and upon Loading with Chiral Guest Compoundscitations
- 2013A mild and efficient approach to functional single-chain polymeric nanoparticles via photoinduced Diels-Alder ligationcitations
- 2013Site-selective growth of surface-anchored metal-organic frameworks on self-assembled monolayer patterns prepared by AFM nanograftingcitations
- 2013On the dielectric and optical properties of surface-anchored metal-organic frameworks: A study on epitaxially grown thin filmscitations
- 2013Systems Chemistry at marginal Interfaces
- 2013Surface anchored metal-organic frameworks as stimulus responsive antifouling coatingscitations
- 2013Post-Synthetic Modification of Metal-Organic Framework Thin Films Using Click Chemistry: The Importance of Strained C-C Triple Bondscitations
- 2012The Biocompatibility of Metal-Organic Framework Coatings: An Investigation on the Stability of SURMOFs with Regard to Water and Selected Cell Culture Mediacitations
Places of action
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article
Oxidative polymerization of terthiophene and a substituted thiophene monomer in metal-organic framework thin films
Abstract
Films consisting of surface-anchored metal-organic frameworks (SURMOFs) which are prepared by layer-by-layer deposition techniques can be used as highly oriented crystalline template structures for oligomerization processes. Herein, SURMOF films of Zn(bdc) (1) and, Cu(bpdc) (2) were prepared, which consist of lamellar ordered 2D MOF sheets forming 1D channels as the host structures for oligomerization of terthiophene (Tth) and, 3,4-ethylenedioxythiophene (EDOT), respectively. After SURMOF preparation, the pores were filled either with Tth or EDOT and the oligomerization was initiated by oxidizing agents, such as I2 and FeCl3. Using matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-ToF/MS), the short chains of polyterthiophene (PTth) and poly(3,4-ethylenedioxythiophene) (PEDOT) were characterized. FT-IR and Raman spectroscopy further confirmed the presence of oligomers inside the pores of the SURMOFs. Using the SURMOF thin films as template, a homogeneously distributed conductive MOF-PEDOT composite coating can be achieved, with potential applications in optoelectronics.