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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Sipponen, Mika H.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2021Multifunctional lignin-based nanocomposites and nanohybridscitations
- 2021Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite filmscitations
- 2020Three-Dimensional Printed Cell Culture Model Based on Spherical Colloidal Lignin Particles and Cellulose Nanofibril-Alginate Hydrogelcitations
- 2019Strong, Ductile, and Waterproof Cellulose Nanofibril Composite Films with Colloidal Lignin Particlescitations
- 2018Elucidating enzymatic polymerisationscitations
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article
Elucidating enzymatic polymerisations
Abstract
<p>The sustainable synthesis of polymers is a field with growing interest due to the need of modern society to preserve the environment whilst making used products and food sustainable for the future generations. In this work we investigate the possibility of synthesizing aliphatic polyesters derived from various dicarboxylic acid diesters and diols in a solvent-free reaction system. Candida antarctica lipase B was selected as biocatalyst and its selectivity towards the carbon and ester chain length were elucidated. The selected enzyme was able to synthesize various polyesters combining C<sub>4</sub>-C<sub>10</sub> diesters and C<sub>4</sub>-C<sub>8</sub> diols. All combinations led to monomer conversions above 90% in 24 h with the best number average molecular weights (M<sub>n</sub>) being obtained through the combination of dimethyl adipate and 1,8-octanediol leading to a M<sub>n</sub> of 7141 Da. Differential scanning calorimetry analysis shows a clear trend with an increase in melting temperature of the polymers that correlates with both the increase of the M<sub>n</sub> or of the polymer's constitutional repeat unit carbon chain length. Thermogravimetric analysis and rheology measurements performed on selected samples also confirm the trend showing a variation of the polymer's degradation temperatures and viscosity profiles.</p>