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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Nugent, Michael J. D.
Athlone Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2024Extraction and characterization of microfibrillated cellulose (MFC) from Rhododendron ponticum isolated using cryocrush pre-treatment and its potential for mycelium cultivationcitations
- 2024Investigation of the effect of Graphene oxide concentration on the final properties of Aspirin loaded PLA filaments for drug delivery systems
- 2023Evaluation of titanium nitride coatings in bandsaw blades for wood splitting by cold plasmacitations
- 2022Plasma electrolytic oxidation up to four-steps performed on niobium and Nb-Ti alloyscitations
- 2021Scratch-resistant and well-adhered nanotube arrays produced via anodizing process on β-titanium alloycitations
- 2021Scratch-resistant and well-adhered nanotube arrays produced via anodizing process on β-titanium alloycitations
- 2021Ti-25Nb-25Ta alloy treated by plasma electrolytic oxidation in phosphoric acid for implant applications
- 2021Ti-25nb-25ta alloy treated by plasma electrolytic oxidation in phosphoric acid for implant applicationscitations
- 2021Development, characterization and cell viability inhibition of pva spheres loaded with doxorubicin and 4′-amino-1-naphthyl-chalcone (D14) for osteosarcomacitations
- 2021Evaluation of titanium nitride coatings in bandsaw blades for wood splitting by cold plasmacitations
- 2020Effect of cellulose size-concentration on the structure of polyvinyl alcohol hydrogelscitations
- 2020Titanium-Niobium (Ti-xNb) Alloys with High Nb Amounts for Applications in Biomaterialscitations
- 2019Titanium-niobium alloys covered by electrospinning technique to applications in bone implants
- 2019Electrospun hydrogels composites for bone tissue engineering.
- 2019The production of a novel poly(vinyl alcohol) hydrogel cryogenic spheres for immediate release using a droplet system.citations
- 2019The production of a novel poly(vinyl alcohol) hydrogel cryogenic spheres for immediate release using a droplet systemcitations
- 2019Photopolymerization for filling porous ceramic matrixcitations
- 2018Electrospun hydrogels composites for bone tissue engineeringcitations
- 2013Effect of slight crosslinking on the mechanical relaxation behavior of poly(2-ethoxyethyl methacrylate) chainscitations
- 2009Development and characterisation of an agar-polyvinyl alcohol blend hydrogelcitations
- 2008Characterisation and controlled drug release from novel drug-loaded hydrogelscitations
- 2007The effect of salts and pH buffered solutions on the phase transition temperature and swelling of thermoresponsive pseudogels based on N-isopropylacrylamidecitations
- 2007The synthesis, swelling behaviour and rheological properties of chemically crosslinked thermosensitive copolymers based on N-isopropylacrylamidecitations
- 2007Preparation of a novel freeze thawed poly(vinyl alcohol) composite hydrogel for drug delivery applicationscitations
- 2006Lower critical solution temperature control and swelling behaviour of physically crosslinked thermosensitive copolymers based on N-isopropylacrylamidecitations
Places of action
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article
Effect of slight crosslinking on the mechanical relaxation behavior of poly(2-ethoxyethyl methacrylate) chains
Abstract
<p>The synthesis, thermal and mechanical characterizations of uncrosslinked and lightly crosslinked poly(2-ethoxyethyl methacrylate) are reported. The uncrosslinked poly(2-ethoxyethyl methacrylate) exhibits in the glassy state two relaxations called in increasing order of temperature, the gamma and beta processes respectively. These are followed by a prominent glass-rubber or alpha relaxation. By decreasing the chains mobility by a small amount of crosslinking, the beta relaxation disappears and the peak maximum associated with the alpha relaxation is shifted from 268 K to 278 K, at 1 Hz. An investigation of the storage relaxation modulus of the crosslinked polymer indicates two inflexion points that presumably are related to segmental motions of dangling chains of the crosslinked networks and to cooperative motions of the chains between crosslinking points. Nanodomains formed by side-groups flanked by the backbone give rise to a Maxwell-Wagner-Sillars relaxation in the dielectric spectra that have no incidence in the mechanical relaxation spectra.</p>