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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gastaldi, Emmanuelle
University of Montpellier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2023Monitoring the degradation status of biodegradable polymers by assessing thermal properties
- 2023Compostability of certified biodegradable plastics at industrial scale processing conditions
- 2022Effects of Kraft lignin and corn cob agro-residue on the properties of injected-moulded biocompositescitations
- 2022Effects of Kraft lignin and corn cob agro-residue on the properties of injected-moulded biocompositescitations
- 2020Multi-faceted migration in food contact polyethylene-based nanocomposite packagingcitations
- 2020How Vine Shoots as Fillers Impact the Biodegradation of PHBV-Based Compositescitations
- 2019How olive pomace can be valorized as fillers to tune the biodegradation of PHBV based compositescitations
- 2019A comparative study of degradation mechanisms of PBSA and PHBV under laboratoryscale composting conditionscitations
- 2019New Insights For The Fragmentation Of Plastics Into Microplastics In The Ocean
- 2019Experimental and theoretical study of the erosion of semi-crystalline polymers and the subsequent generation of microparticles.citations
- 2018Fast-Biodegrading polymers
- 2018Soy protein isolate nanocomposite film enriched with eugenol, an antimicrobial agent: Interactions and propertiescitations
- 2018Soy protein isolate nanocomposite film enriched with eugenol, an antimicrobial agent: Interactions and propertiescitations
- 2018Nanostructured biopolymers obtained from blends by extrusion
- 2018How Performance and Fate of Biodegradable Mulch Films are Impacted by Field Ageingcitations
- 2017Contribution of nanoclay to the additive partitioning in polymerscitations
- 2016Effect of nanoclay on the transfer properties of immanent additives in food packagescitations
- 2013Water transport mechanisms in wheat gluten based (nano) composite materialscitations
- 2013Nanoparticle size and water diffusivity in nanocomposite agro-polymer based filmscitations
- 2013Nanoparticle size and water diffusivity in nanocomposite agro-polymer based filmscitations
- 2013Protein-Based Nanocomposites for Food Packagingcitations
- 2013Biocomposites from wheat proteins and fibers: Structure/mechanical properties relationshipscitations
- 2013Adhesion properties of wheat-based particlescitations
- 2012Protein/Clay Nano-Biocompositescitations
- 2011Impact of high pressure treatment on the structure of montmorillonitecitations
- 2010Réduction de l'impact de l’utilisation des produits phytosanitaires: Contrôle de la libération dans le sol par un granulé protéique biodégradable nanocomposite
- 2010Synthesis of nanocomposite films from wheat gluten matrix and MMT intercalated with different quaternary ammonium salts by way of hydroalcoholic solvent castingcitations
Places of action
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article
Nanoparticle size and water diffusivity in nanocomposite agro-polymer based films
Abstract
Nanocomposite films were prepared by a thermo-mechanical process from wheat gluten (WG) and unmodified montmorillonite (MMT). The present work aims at predicting the relationships between the decrease in relative diffusivity of liquid water and the structure of the nanocomposite films, from in situ evaluation of the MMT size aspect ratio and volume fraction, and by using a simple tortuous path mathematical model. The modelling approach first allowed predicting and validating the tortuosity effect of MMT particles on liquid water transport properties of WG-based films. In spite of a well-exfoliated nanocomposite structure, the liquid water diffusivity in WG-based films can at best be decreased by a factor of 2 with this type of clay nanoparticle, which was in agreement with the Bharadwaj model predictions. This study underlines the necessity to achieve a totally exfoliated nanocomposite structure, and above all, to select layered silicates displaying higher size aspect ratio values in order to efficiently improve water barrier properties of WG-based nanocomposite films. Furthermore, the extremely complex structure of nanocomposite materials makes detailed morphological studies often difficult, time and cost consuming. (c) 2012 Elsevier Ltd. All rights reserved.