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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zia, Abdul Wasy
Heriot-Watt University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Innovative Tin and hard carbon architecture for enhanced stability in lithium-ion battery anodescitations
- 2024Sputtered Hard Carbon for High-Performance Energy Storage Batteries
- 2024Designing Molybdenum Trioxide and Hard Carbon Architecture for Stable Lithium‐Ion Battery Anodescitations
- 2024Wear-resistant and adherent nanodiamond composite thin film for durable and sustainable silicon carbide mechanical seals.citations
- 2024Circular usage of waste cooking oil towards green electrical discharge machining process with lower carbon emissionscitations
- 2024Oxygen concentration – a governing parameter for microstructural tailoring of duplex AlCrSiON coatings for superior mechanical, tribological, and anti-corrosion performancecitations
- 2024Wear-resistant and Adherent Nanodiamond Composite Thin Film for Durable and Sustainable Silicon Carbide Mechanical Sealscitations
- 2024Role of scandium addition to microstructure, corrosion resistance, and mechanical properties of AA7085/ZrB2+Al2O3 compositescitations
- 2024Precision depth-controlled isolated silver nanoparticle-doped diamond-like carbon coatings with enhanced ion release, biocompatibility, and mechanical performancecitations
- 2023Soft diamond-like carbon coatings with superior biocompatibility for medical applicationscitations
- 2023Multi-layered Sn and Hard Carbon Architectures for Long-Term Stability and High-Capacity Lithium-Ion Battery Anodes
- 2023Role of biodegradable dielectrics toward tool wear and dimensional accuracy in Cu-mixed die sinking EDM of Inconel 600 for sustainable machiningcitations
- 2023Role of biodegradable dielectrics toward tool wear and dimensional accuracy in Cu-mixed die sinking EDM of Inconel 600 for sustainable machining
- 2023Advancing Lithium-Ion Battery Anodes: Novel Sn and Hard Carbon Architectures for Long-Term Stability and High Capacity
- 2022Disrupting biofilm and eradicating bacteria by Ag-Fe3O4@MoS2 MNPs nanocomposite carrying enzyme and antibioticscitations
- 2013Epitaxial growth of cerium oxide thin films by pulsed laser depositioncitations
- 2013Effect of Diamond like Carbon Coating Thickness on Stainless Steel Substrate
- 2012 Fracture Toughness of Plasma Coated Zirconia(ZrO₂)
- 2012Mechanical Characterization of PECVD coated Materials by Indentation Techniques and Finite Element Simulation
Places of action
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article
Innovative Tin and hard carbon architecture for enhanced stability in lithium-ion battery anodes
Abstract
Tin (Sn), with a theoretical capacity of 994 mAh g-1, is a promising anode material for lithium-ion batteries (LIBs). However, fundamental limitations like large volume expansion during charge-discharge cycle and confined electronic conductivity limit its practical utility. Here, we report a new material design and manufacturing method of LIB anodes using Sn and Hard Carbon (HC) architecture, which is produced by Physical Vapor Deposition (PVD). A bilayer HC/Sn anode structure is deposited on a carbon/copper sheet as a function of deposition time, temperature, and substrate heat treatment. The developed anodes are used to make cells with a lithium-ion electrolyte using a specific fabrication process. The morphology, atomic structure, conductivity, and electrochemical performance of the developed HC/Sn anodes are studied with SEM, TEM, XPS, and electrochemical techniques. At a discharge rate of 0.1C, the Snheated + HC anode performs exceptionally well, offering a capacity of 763 mAh g-1. It is noteworthy that it achieves a capacity of 342 mAh g-1 when fast charging at 5C, demonstrating exceptional rate capability. The Snheated + HC anode maintains >97 % Coulombic efficiency of its capacity after 3000 cycles at a rate of 0.1C after 3000 cycles 730.5 mAh g-1 recorded, demonstrating an impressive cycle life. The novel material design approach of the Snheated + HC anode, which has a multi-layered structure and HC acting as a barrier against volumetric expansion and improving electronic conductivity during battery cycling, is perceived as influential in uplifting anode's performance.