• Alawadhi, Hussain
• Abdelkareem, Mohammad Ali
• Olabi, Abdul Ghani
• Bahaa, Ahmed
• Rodriguez, Cristina
• Elsaid, Khaled
• Adil, M.

Abstract

Since 2D MXene offers high conductivity and high redox-active sites making it an excellent candidate for supercapacitors (SCs). On the other hand, metal-organic frameworks (MOF) derived 3D nanospheres like CoS have their own distinctive merits such as high porosity, abundant active sites, large surface area, and superior electrochemical properties. Herein, a novel strategy has been opted to fabricate MXene cobalt sulfide (MXene-CoS). For the first time MOF derived CoS nanostructures were successfully incorporated with MXene flakes and grown on porous nickel foam. Consequently, the electroactivity of the as-prepared electrodes was enhanced by dwindling the ion-electron diffusion pathways. MXene-CoS/AC asymmetric device operated at a wide potential window of 1.6 V which is among the widest for MXene based SCs. The prepared electrodes demonstrated ultra-high specific capacity of 447 mA h g⁻¹ at a current density of 3 mA cm⁻². The assembled MXene-CoS/AC ASC solid-state device manifested a high specific capacity of ~190 mA h g⁻¹ and volumetric capacity of 1.2 mA h cm⁻³ at a current density of 2 mA cm⁻². The presented strategy paves a way for a new dimension of MOF-derived metal sulfides incorporated with 2D MXene for high-performance SCs with excellent cyclic stability.

Topics

• porous
• density
• impedance spectroscopy
• surface
• nickel
• cobalt
• current density
• porosity