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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Khalid, Mohammad
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Influence of Dilution Upon the Ultraviolet-Visible Peak Absorbance and Optical Bandgap Estimation of Tin(IV) Oxide and Tin(IV) Oxide-Molybdenum(IV) Sulfide Solutionscitations
- 2023Facile and Affordable Design of MXene‐Co<sub>3</sub>O<sub>4</sub>‐Based Nanocomposites for Detection of Hydrogen Peroxide in Cancer Cells: Toward Portable Tool for Cancer Managementcitations
- 2023Impacts of annealing temperature and time on the thermoelectric performance of recycled carbon fiber (RCF)/n-Bi2Te3 heterostructure thermoelectric composites.
- 2022Internet-of-nano-things (IoNT) driven intelligent face masks to combat airborne health hazard
- 2022Internet-of-nano-things (IoNT) driven intelligent face masks to combat airborne health hazardcitations
- 2022Tailoring crystallinity of 2D cobalt phosphate to introduce pseudocapacitive behaviorcitations
- 2022Comprehensive review on carbon nanotubes embedded in different metal and polymer matrix: fabrications and applicationscitations
- 2022Microwave assisted synthesis of Mn3O4 nanograins intercalated into reduced graphene oxide layers as cathode material for alternative clean power generation energy devicecitations
- 2022Development of Dapagliflozin Solid Lipid Nanoparticles as a Novel Carrier for Oral Delivery: Statistical Design, Optimization, In-Vitro and In-Vivo Characterization, and Evaluationcitations
- 2022Three-Dimensional Graphene-TiO2-SnO2Ternary Nanocomposites for High-Performance Asymmetric Supercapacitorscitations
- 2022Emergence of MXene–olymer hybrid nanocomposites as high-performance next-generation chemiresistors for efficient air quality monitoringcitations
- 2021Comprehensive review on carbon nanotubes embedded in different metal and polymer matrix: fabrications and applicationscitations
- 2019Effective devulcanization of ground tire rubber using choline chloride-based deep eutectic solventscitations
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article
Tailoring crystallinity of 2D cobalt phosphate to introduce pseudocapacitive behavior
Abstract
<p>The latest technological developments have catalyzed the quest for efficient electrochemical energy storage devices. Tailoring the properties of the electrode materials, such as porosity, crystallinity, electrochemical surface area, etc., can enhance the performance of electrochemical energy devices. Herein, the sonochemical synthesis of cobalt phosphate (Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>) followed by calcination at various temperatures (at 200, 400, 600, and 800 °C) is reported. The effect phase transformation of Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub> at various calcination temperatures on its electrochemical performance is evaluated. The prepared Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub> samples were characterized by analytical techniques such as X-ray diffraction spectroscopy (XRD), X-ray Photoelectron Spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), field emission scanning electrons microscopy (FESEM), and energy-dispersive X-ray spectroscopy (EDS). The FESEM results showed morphological changes when Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub> is calcined at 200, 400, 600, and 800 °C. XRD pattern revealed the phase transformations from crystalline to amorphous and then again crystalline due to the loss of water molecules from the crystal structure Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>. The EDS provided the elemental analysis and confirmed the high purity of the samples under investigation. The change in electrochemical behavior of the prepared samples was examined in a three-electrode cell using 1 M potassium hydroxide (KOH) electrolyte using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. The Co<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub> calcined at 200 °C demonstrated excellent electrochemical performance, giving a specific capacity of 352.00 C·g<sup>−1</sup>, selected for the fabrication of supercapattery. The fabricated supercapattery (Co<sub>3</sub>(PO<sub>4</sub>)<sub>2:</sub>@200 °C//AC) produced 51.95 Wh·kg<sup>−1</sup> energy density corresponding to the power density of 346.00 W·kg<sup>−1</sup> at a current density of 1.0 A g<sup>−1</sup>.</p>