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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kannan, Pravin
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Publications (5/5 displayed)
- 2024Comparative energy, emissions and economic assessment of low-carbon iron and steel making processes using imported liquid organic hydrogen carrier optionscitations
- 2023Power to gas and top gas recycling integration in an oxygen blast furnace steelmaking industrycitations
- 2021Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO2/porous graphitic carbon as adsorbentcitations
- 2021Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO 2 /porous graphitic carbon as adsorbentcitations
- 2020Design of adsorption column for reclamation of methyldiethanolamine using homogeneous surface diffusion modelcitations
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article
Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO2/porous graphitic carbon as adsorbent
Abstract
A facile hydrothermal assisted in-situ precipitation technique was employed for synthesizing highly efficient porous graphitic carbon/manganese dioxide (PGC/MnO<sub>2</sub>) nanocomposite adsorbent using calcium alginate as carbon precursor. Morphological and structural characterization using scanning electron microscopy equipped with energy dispersive X-ray spectroscopy, transmission electron microscopy, and X-ray diffraction techniques confirmed the interconnected nanoporous architecture and birnessite (<i>δ</i>) MnO<sub>2</sub> polymorph evenly distributed on the PGC structure. The synergistic effect of PGC and MnO<sub>2</sub> was exploited for enhanced sulfide removal from wastewater via adsorptive oxidation. The effect of different experimental parameters, including solution pH, initial sulfide concentration, adsorbent dosage, and contact time on removal efficiency was investigated. The equilibrium and kinetic data for sulfide adsorption by PGC/MnO<sub>2 </sub>nanocomposite fitted well with Langmuir isotherm and pseudo-second-order kinetic model, respectively. The maximum uptake capacity of sulfide by the nanocomposite was determined as 500 mg/g with complete sulfide removal. Further, it was estimated that a typical field application using the synthesized nanocomposite adsorbent would require 0.5–1 g/L per 200 mg/L of sulfide contaminated wastewater. Based on the experimental results, a schematic of the adsorptive oxidation mechanism of PGC/MnO<sub>2</sub> nanocomposite is proposed.