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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Edathil, Anjali Achazhiyath
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
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Publications (5/5 displayed)
- 2024In-situ mineralization of biomass-derived hydrogels boosts capacitive electrochemical energy storage in free-standing 3D carbon aerogelscitations
- 2021Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO2/porous graphitic carbon as adsorbentcitations
- 2021Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO 2 /porous graphitic carbon as adsorbentcitations
- 2020Chicken feathers as an intrinsic source to develop ZnS/carbon composite for Li-ion battery anode materialcitations
- 2020Chicken feathers as an intrinsic source to develop ZnS/carbon composite for Li-ion battery anode materialcitations
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article
Sulfide remediation from wastewater using hydrothermally synthesized δ-MnO2/porous graphitic carbon as adsorbent
Abstract
A facile hydrothermal assisted in-situ precipitation technique was employed for synthesizing highly efficient porous graphitic carbon/manganese dioxide (PGC/MnO<sub>2</sub>) nanocomposite adsorbent using calcium alginate as carbon precursor. Morphological and structural characterization using scanning electron microscopy equipped with energy dispersive X-ray spectroscopy, transmission electron microscopy, and X-ray diffraction techniques confirmed the interconnected nanoporous architecture and birnessite (<i>δ</i>) MnO<sub>2</sub> polymorph evenly distributed on the PGC structure. The synergistic effect of PGC and MnO<sub>2</sub> was exploited for enhanced sulfide removal from wastewater via adsorptive oxidation. The effect of different experimental parameters, including solution pH, initial sulfide concentration, adsorbent dosage, and contact time on removal efficiency was investigated. The equilibrium and kinetic data for sulfide adsorption by PGC/MnO<sub>2 </sub>nanocomposite fitted well with Langmuir isotherm and pseudo-second-order kinetic model, respectively. The maximum uptake capacity of sulfide by the nanocomposite was determined as 500 mg/g with complete sulfide removal. Further, it was estimated that a typical field application using the synthesized nanocomposite adsorbent would require 0.5–1 g/L per 200 mg/L of sulfide contaminated wastewater. Based on the experimental results, a schematic of the adsorptive oxidation mechanism of PGC/MnO<sub>2</sub> nanocomposite is proposed.