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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mazur, Michal
Charles University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Exfoliating layered zeolite MFI into unilamellar nanosheets in solution as precursors for the synthesis of hierarchical nanocomposites and oriented filmscitations
- 2022Direct dehydrogenation of propane over Pd nanoparticles encapsulated within IPC zeolites with tunable pore sizes ; Přímá dewhydrogenace propanu na Pd nanočásticích zapouzdřených uvnitř IPC zeolitu s volitelnou velikostí pórůcitations
- 2021Controlled synthesis of large single crystals of metal-organic framework CPO-27-Ni prepared by a modulation approach : in situ single crystal X-ray diffraction studiescitations
- 2021Controlled synthesis of large single crystals of metal-organic framework CPO-27-Ni prepared by a modulation approach: in situ single crystal X-ray diffraction studiescitations
- 2020Effect of physical activation/surface functional groups on wettability and electrochemical performance of carbon/activated carbon aerogels based electrode materials for electrochemical capacitorscitations
- 2020Core–Shell Metal Zeolite Composite Catalysts for In Situ Processing of Fischer–Tropsch Hydrocarbons to Gasoline Type Fuelscitations
- 2019Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applicationscitations
- 2019Vapour-phase-transport rearrangement technique for the synthesis of new zeolitescitations
- 2018Zeolite framework functionalisation by tuneable incorporation of various metals into the IPC-2 zeolitecitations
- 2017Modification of various properties of HfO2 thin films obtained by changing magnetron sputtering conditionscitations
- 2016Investigation of various properties of HfO2-TiO2 thin film composites deposited by multi-magnetron sputtering systemcitations
- 2015Investigation of structural, optical and micro-mechanical properties of (NdyTi1-y)O-x thin films deposited by magnetron sputteringcitations
Places of action
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article
Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications
Abstract
Nitrogen doped resorcinol/formaldehyde carbon aerogels with controlled nitrogen content are synthesized by controlling the resorcinol/melamine molar ratio (R/M) during the synthesis of aerogel precursors. The carbons were used as electrode materials in an electrochemical capacitor using 6M KOH solution as electrolyte. All samples exhibited amorphous structure with low degree of graphitization. The maximum specific capacitance of 208 Fg-1 was observed after doping of the carbon with nitrogen at R/M = 80. Drop in solution and charge transfer resistances from 0.57Ω to 0.15Ω and 0.05Ω to 0.04Ω was also observed respectively, with the drop in contact angles from 123º to 103º for the carbon doped with nitrogen at R/M = 80. BET results showed that the pore volume and surface area of carbon increase after N-doping, with a BET surface area of 841 m2 g-1 at R/M = 80.This R/M ratio is an optimum ratio at which incorporation of nitrogen into the carbon matrix improves the capacitive performance of cell as a result of improved porosity/wettability/conductivity/active sites of the electrode. Doping at higher nitrogen concentrations (R/M < 80) decreased the specific capacitance of the cell significantly due to decreased conductivity of carbon and suppression of the hopping rate of dopant.